Synthesis of pyridine ligands via transient organomercurials was written by Canty, Allan J.;Minchin, Nigel J.. And the article was included in Inorganica Chimica Acta in 1985.Synthetic Route of C8H11N This article mentions the following:
Dimerization of RCH(CH3)2 (R = 2-pyridyl), RCH2C6H5, RCH(CH3)C6H5, and R2CH2 was accomplished in 16-85% nonoptimized yields via successive reactions with BuLi-hexane-THF, HgI2-THF, and H2O. Pd2(OAc)4(R2CHCHR2) and Pd(OAc)2[RCH(C6H5)CH(C6H5)R] were prepared; they contain tetradentate bridging/chelate and bidentate chelate pyridine ligands resp., and monodentate acetate. In the experiment, the researchers used many compounds, for example, 2-Isopropylpyridine (cas: 644-98-4Synthetic Route of C8H11N).
2-Isopropylpyridine (cas: 644-98-4) belongs to pyridine derivatives. Pyridine is diamagnetic and has a diamagnetic susceptibility of −48.7 × 10−6 cm3·mol−1.The molecular electric dipole moment is 2.2 debyes. The standard enthalpy of formation is 100.2 kJ·mol−1 in the liquid phase and 140.4 kJ·mol−1 in the gas phase. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Synthetic Route of C8H11N