Facile C-H arylation using catalytically active terminal sulfurs of 2 dimensional molybdenum disulfide was written by Hwang, Eunhee;Mi Lee, Sae;Bak, Sora;Min Hwang, Hee;Kim, Hyunjung;Lee, Hyoyoung. And the article was included in Tetrahedron Letters in 2018.Application of 4373-61-9 This article mentions the following:
The first methodol. of C-H arylation of heteroarene via 2D transition metal dichalcogenides that have catalytically active edge functional groups was described. The terminal sulfur groups could effectively catalyze a formation of an azo-linked intermediate with aryl diazonium salts, leading to produce heteroarenes with good yields. This novel methodol. using bulk 2D transition metal dichalcogenides that have catalytically active edge functional groups can apply for various reactions to achieve C-C bond formation in the fields of heterogeneous catalysis that is easily separable, highly reusable, and inexpensive method. In the experiment, the researchers used many compounds, for example, 2-(m-Tolyl)pyridine (cas: 4373-61-9Application of 4373-61-9).
2-(m-Tolyl)pyridine (cas: 4373-61-9) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. One of the examples of pyridines is the well-known alkaloid lithoprimidine, which is an A3 adenosine receptor antagonist and N,N-dimethylaminopyridine (DMAP) analog, commonly used in organic synthesis.Application of 4373-61-9