Alkylation of pyridine in free radical chain reactions utilizing alkylmercurials was written by Russell, Glen A.;Guo, Deliang;Khanna, Rajive K.. And the article was included in Journal of Organic Chemistry in 1985.HPLC of Formula: 644-98-4 This article mentions the following:
Pyridines or N,N,N‘,N‘-tetramethyl-p-phenylenediamine will undergo a photostimulated free radical chain reaction with alkylmercury halides or carboxylates yielding ring alkylated substitution products. Alkene mercuration products can be used without isolation for the alkylation reaction. In the experiment, the researchers used many compounds, for example, 2-Isopropylpyridine (cas: 644-98-4HPLC of Formula: 644-98-4).
2-Isopropylpyridine (cas: 644-98-4) belongs to pyridine derivatives. The ring atoms in the pyridine molecule are sp2-hybridized. The nitrogen is involved in the 锜?bonding aromatic system using its unhybridized p orbital. The lone pair is in an sp2 orbital, projecting outward from the ring in the same plane as the 锜?bonds. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. HPLC of Formula: 644-98-4