The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 614-18-6, Name is Ethyl nicotinate, SMILES is O=C(OCC)C1=CN=CC=C1, in an article , author is Shukla, Satyendra Nath, once mentioned of 614-18-6, Name: Ethyl nicotinate.
Pd(II) complexes with ONN pincer ligand: Tailored synthesis, characterization, DFT, and catalytic activity toward the Suzuki-Miyaura reaction
A pincer type ONN tridentate Schiffbase ligand, 2-(((pyridin-2-yl)methylimino)methyl)-6-methoxyphenol, (L-1) synthesized by the condensation of 4-hydroxy-3-methoxy-benzaldehyde and (pyridin-2-yl)methanamine. The ligand L-1 and the new Pd(II) heteroleptic complexes of the composition [Pd(L-1)(L-2)]Cl, where L-2 = benzimidazole, imidazole, benzooxazol or pyridine were synthesized and characterized by a set of chemical, spectrometric and spectroscopic analyses. These complexes were named 1 to 4, respectively. The FT-IR and DFT have suggested that ligand is coordinated with metal through azomethine-N and phenolic-O and arranged in square planar fashion around the metal. Correlation coefficients value between 0.995 – 0.993 shows satisfactory agreement in theoretical and experimental H-1-NMR and C-13-NMR. Benzimidazole anchored complex 1 exhibits an excellent catalytic activity. DFT calculated the energy profile diagram of the Suzuki-Miyaura reaction. (C) 2020 Elsevier B.V. All rights reserved.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem