In an article, author is Gautam, Achar, once mentioned the application of 877399-00-3, Name is (R)-5-Bromo-3-(1-(2,6-dichloro-3-fluorophenyl)ethoxy)pyridin-2-amine, molecular formula is C13H10BrCl2FN2O, molecular weight is 380.04, MDL number is MFCD18207061, category is pyridine-derivatives. Now introduce a scientific discovery about this category, Application In Synthesis of (R)-5-Bromo-3-(1-(2,6-dichloro-3-fluorophenyl)ethoxy)pyridin-2-amine.
Palladium(II) complexes of coumarin substituted 1,2,4-triazol-5-ylidenes for catalytic C-C cross-coupling and C-H activation reactions
Two series of palladium complexes of the type [PdBr2(NHC)(2)] (4-6) and [PdBr2(NHC)Py] (7-9) bearing coumarin substituted triazole-based NHC ligands have been reported. Complexes have been prepared by in situ deprotonation of 1,2,4-triazolium salts with palladium acetate in DMSO/pyridine, and characterized by spectral and analytical techniques. The complexes displayed a distorted square-planar coordination geometry around the palladium atom, which is evidenced by the single crystal X-ray diffraction analysis of 4-6 and 9 . Both the series of complexes have been evaluated for their efficacies in C-C bond formation reactions of various aryl bromides with phenylboronic acid, and C-H activation reactions of thiophene substituted cyanopyridine derivative. Complexes 7-9 outperformed the bis-NHC coordinated derivatives, 4-6 , in both the type of catalytic reactions, which is attributed to the presence of a labile pyridine ligand. (C) 2020 Elsevier B.V. All rights reserved.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem