Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Mori, Daiki, once mentioned the application of 128071-98-7, Name is 4-Bromo-2-fluoropyridine, molecular formula is C5H3BrFN, molecular weight is 175.99, MDL number is MFCD04112504, category is pyridine-derivatives. Now introduce a scientific discovery about this category, Name: 4-Bromo-2-fluoropyridine.
meso-Diketopyripentaphyrin and Diketopyrihexaphyrin as Macrocyclic Tripyrrinone Ligands for Ni-II Ions
We report expanded porphyrins with pyridine rings and two neighboring carbonyl groups, which allow Ni-II ions to coordinate to the tripyrrinone-type NNNO coordination structure with Ni-O bonds. The selectivity of tripyrrinone is superior to other pyrrolic or pyridinic cavities of expanded porphyrins. Introduction of alpha-carbonyl pyridine next to the tripyrrolic conjugated structure is a powerful strategy for regioselective metalation of flexible expanded porphyrinoids.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem