The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 89-00-9, Name is Pyridine-2,3-dicarboxylic acid, SMILES is O=C(C1=NC=CC=C1C(O)=O)O, in an article , author is Rivoira, Lorena P., once mentioned of 89-00-9, Category: pyridine-derivatives.
Catalytic oxidation of sulfur compounds over Ce-SBA-15 and Ce-Zr-SBA-15
The catalytic oxidation of different sulfur compounds, commonly present in liquid fuel, was studied over a series of ceria and ceria-zirconium based oxidation mesoporous catalysts. SBA-15 was synthesized using sol-gel method and Ce and Ce-Zr were added by two different procedures: i) directly during the synthesis and ii) via post synthesis method. The catalysts were characterized by XRD, N-2 adsorption isotherms, XPS, DRUV-Vis, TEM, SEM and Py-FTIR. Low angle XRD, N-2 isotherms and TEM confirmed that the structure was not changed after metal incorporation. Wide angle XRD, UV-vis-DRS, XPS and TEM determined that the catalysts prepared by direct synthesis presented higher dispersion of Ce oxides, smaller particle size and isolated Zr4+ species. FTIR of adsorbed/desorbed pyridine indicated that zirconium as promoter increases the Lewis acidity of the catalysts, especially during direct synthesis. Ce-Zr-SBA-15 catalyst prepared by direct synthesis was very active in the oxidation of dibenzothiophene, 4,6-dimethyl dibenzothiophene and benzothiophene using hydrogen peroxide (H2O2) as oxidant agent and acetonitrile as polar solvent. The effect of acidity in the catalyst, hydrogen peroxide concentration and temperature was studied. The deactivation test demonstrated that the catalyst is stable and adequate for the industrial process.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem