Application of 1195-59-1, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 1195-59-1, Name is 2,6-Pyridinedimethanol, SMILES is OCC1=NC(CO)=CC=C1, belongs to pyridine-derivatives compound. In a article, author is Lu, Dongmei, introduce new discover of the category.
Electronic structure of mono(Lewis base)-stabilized borylenes
This work demonstrates that the mono(Lewis base)-stabilized three-center-six-electron (3c-6e) or LB -> B-R type borylenes may have a ground state singlet (sigma(2)pi(0) and sigma(0)pi(2)) or triplet (sigma(1)pi(1)) electronic structure, depending on the substitution group, Lewis base, and molecule topology (cyclic or acyclic). The singlet-triplet energy gap of a borylene increases with electron-donating substitution groups and decreases with Lewis bases of strong sigma-donating and pi-accepting feature (e.g., carbenes and pyridine). The gap can be widely varied (ranging up to about 300 kJ mol(-1)) and even inversed by the proper combination of substitution groups and Lewis bases. These borylenes may even have singlet-and-triplet coexisting ground state electronic structures, which imply their complex reactivity.
Application of 1195-59-1, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 1195-59-1 is helpful to your research.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem