19524-06-2, Name is 4-Bromopyridine hydrochloride, molecular formula is C5H5BrClN, belongs to pyridine-derivatives compound, is a common compound. In a patnet, author is Singh, Ovender, once mentioned the new application about 19524-06-2, Formula: C5H5BrClN.
A new family of complexes derived from bis(imino)pyridine-type ligands: Crystal structures and bio-molecular interaction studies
Bis(imino)pyridine (NNN)-type ligand [(PyPhime-Cina) = 2,6-bis((E)-1-phenyl-2-((E)-3-phenylallylidene)hydrazinyl)pyridine] was synthesized, and a new family of metal complexes [Mn(PyPhime-Cina)Cl2] (1), [Fe(PyPhime-Cina)Cl2] (2), [Co(PyPhime-Cina)Cl2] (3), [Ni(PyPhime-Cina)Cl2] (4), and [Cu(PyPhime-Cina)Cl2] (5), derived from the ligand, have been synthesized and characterized. Molecular structures of the ligand and complexes 1-5 were determined using X-ray crystallography. Electronic properties and frontier molecular orbitals of the complexes were investigated by DFT and TD-DFT calculations. DNA interaction studies were evaluated by UV-visible absorption, fluorescence and circular dichroism spectral studies which indicated noncovalent binding of complexes with CT-DNA. Hirshfeld surface analysis of all the complexes was studied to know the weak interaction present in the molecules.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem