A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Safety of 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin-2(1H)-one, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 503615-03-0, Name is 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin-2(1H)-one, molecular formula is C15H17N3O4. In an article, author is Guthardt, Robin,once mentioned of 503615-03-0.
N-heterocyclic olefins as dative carbon donor ligands for diaminoplumbylenes: Syntheses and crystal structures of adducts with 1,3,4,5-tetramethyl-2-methyleneimidazoline
The aim of this study was to shed more light on the potential of N-heterocyclic olefins as carbon donor ligands for the coordination/stabilization of divalent Group 14 element compounds. Stable adducts of the N-heterocyclic olefin 1,3,4,5-tetramethyl-2-methyleneimidazoline (MeIMeCH2) were isolated with the cyclic diaminoplumbylenes ph(NSiMe3)(2)Pb (ph = 1,2-phenylene) and fc(NSiRMe2)(2)Pb (fc = 1,10-ferrocenylene; R = Me, tBu) as well as with the acyclic congener [(Me3Si)(2)N](2)Pb. In contrast, the cyclic (alkyl)(amino)carbene 1-(2,6-diisopropylphenyl)-3,3-diethyl-5,5-dimethylpyrrolidin-2-ylidene (CAAC(Et)) gave rise to a stable adduct only with ph(NSiMe3)(2)Pb. The ferrocene-based N-heterocyclic olefin fc (NCH(2)tBu)(2)CCH2 was synthesised. It afforded a stable adduct with triphenylborane, but not with the diaminoplumbylenes of this study. All stable adducts were structurally characterized by single-crystal X-ray diffraction. An essentially perpendicular orientation of the Pb-C bond vector with respect to the PbN2 plane was found for the diaminoplumbylene adducts. Pb-207 NMR spectroscopic data suggest, but do not prove, that the strength of the donor-acceptor interaction of the (IMeCH2)-I-Me adducts is lower than that of adducts with the related N-heterocyclic carbene 1,3,4,5-tetramethylimidazolin-2-ylidene, but higher than that of adducts with the popular N-donor 4-(dimethylamino)pyridine. (C) 2020 Elsevier Ltd. All rights reserved.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem