An article Metal-free nitrogen -doped carbon nanosheets: a catalyst for the direct synthesis of imines under mild conditions WOS:000468627300030 published article about ORDERED MESOPOROUS CARBON; ONE-POT; TANDEM SYNTHESIS; OXIDATIVE SYNTHESIS; METHANOL OXIDATION; ORGANIC FRAMEWORK; AEROBIC OXIDATION; EFFICIENT; AMINES; NANOPARTICLES in [Wang, Kaizhi; Jiang, Pengbo; Yang, Ming; Ma, Ping; Qin, Jiaheng; Huang, Xiaokang; Ma, Lei; Li, Rong] Lanzhou Univ, SKLAOC, Lanzhou 730000, Gansu, Peoples R China; [Wang, Kaizhi; Jiang, Pengbo; Yang, Ming; Ma, Ping; Qin, Jiaheng; Huang, Xiaokang; Ma, Lei; Li, Rong] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Gansu, Peoples R China in 2019, Cited 77. The Name is 3-Pyridinecarboxaldehyde. Through research, I have a further understanding and discovery of 500-22-1. Computed Properties of C6H5NO
Herein, a highly stable, porous, multifunctional and metal-free catalyst was developed, which exhibited significant catalytic performance in the oxidation of amines and transfer hydrogenation of nitriles under mild conditions; this could be attributed to the presence of numerous active sites and their outstanding BET surface area. The obtained results showed that most of the yields of imines exceeded 90%, and the cycling performance of the catalyst could be at least seven runs without any decay in the reaction activity, which could be comparable to those of metal catalysts. Subsequently, a kinetic study has demonstrated that the apparent activation energy for the direct synthesis of imines from amines is 67.39 kJ mol(-1), which has been performed to testify that the catalytic performances are rational. Via catalyst characterizations and experimental data, graphitic-N has been proven to be the active site of the catalyst. Hence, this study is beneficial to comprehend the mechanism of action of a metal-free N-doped carbon catalyst in the formation of imines.
Computed Properties of C6H5NO. About 3-Pyridinecarboxaldehyde, If you have any questions, you can contact Wang, KZ; Jiang, PB; Yang, M; Ma, P; Qin, JH; Huang, XK; Ma, L; Li, R or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem