I found the field of Chemistry very interesting. Saw the article Direct intramolecular carbon(sp(2))-nitrogen(sp(2)) reductive elimination from gold(III) published in 2019.0. Quality Control of Phenyl(pyridin-2-yl)methanone, Reprint Addresses Awuah, SG (corresponding author), Univ Kentucky, Dept Chem, 505 Rose St, Lexington, KY 40506 USA.. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone
The reactivity of bidentate Au-III-Cl species, [(C<^>N)AuCl2], with a bisphosphine or carbon donor ligands results in reductive elimination. Combined experimental and computational investigations lead to the first evidence of a direct intramolecular C(sp(2))-N(sp(2)) bond formation from a monomeric [(C<^>N)AuCl2] gold(iii) complex. We show that bidentate ligated Au(iii) systems bypass transmetallation to form C(sp(2))-N(sp(2)) species and NHC-Au-Cl. Mechanistic investigations of the reported transformation reveal a ligand-induced reductive elimination via a key Au-III intermediate. Kinetic studies of the reaction support a second-order rate process.
Quality Control of Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Kim, JH; Mertens, RT; Agarwal, A; Parkin, S; Berger, G; Awuah, SG or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem