Quality Control of 3-Pyridinecarboxaldehyde. Recently I am researching about SOLVENT-FREE HYDROBORATION; COMPLEXES SYNTHESES; MAGNESIUM, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772093]; Natural Science Foundation of Jiangsu Province, ChinaNatural Science Foundation of Jiangsu Province [BK20181421]. Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Wang, WF; Lu, K; Qin, Y; Yao, WW; Yuan, DD; Pullarkat, SA; Xu, L; Ma, MT. The CAS is 500-22-1. Through research, I have a further understanding and discovery of 3-Pyridinecarboxaldehyde
Simple, commercially available Grignard reagents have been used as highly efficient precatalysts for the hydroboration of a wide range of aldehydes and ketones. The reaction employs very low catalyst loadings (aldehydes: 0.05 mol%, ketones: 0.5 mol%), and proceeds rapidly (aldehydes: 10 min, ketones: 20 min) under neat condition at room temperature. The Grignard reagent catalyst demonstrated good substrate scope, functional group tolerance, and high chemoselectivity in the carbonyl hydroboration. DFT calculations were performed to investigate the possible reaction mechanism. In contrast to the traditional stoichiometric use of Grignard reagents, this newly developed protocol provides a catalytic application of these reagents for molecular transformations. (C) 2020 Elsevier Ltd. All rights reserved.
Quality Control of 3-Pyridinecarboxaldehyde. About 3-Pyridinecarboxaldehyde, If you have any questions, you can contact Wang, WF; Lu, K; Qin, Y; Yao, WW; Yuan, DD; Pullarkat, SA; Xu, L; Ma, MT or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem