Recommanded Product: 91-02-1. Danelli, P; Tsantis, ST; Kitos, A; Psycharis, V; Raptopoulou, CP; Tsipis, A; Perlepes, SP in [Danelli, Panagiota; Tsantis, Sokratis T.; Kitos, Alexandros; Perlepes, Spyros P.] Univ Patras, Dept Chem, Patras 26504, Greece; [Psycharis, Vassilis; Raptopoulou, Catherine P.] NCSR Demokritos, Inst Nanosci & Nanotechnol, Aghia Paraskevi 15310, Greece; [Tsipis, Athanassios] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece published Investigating the isolation and interconversion of two diastereoisomers in an octahedral Ni(II)A(2)((BC)over-cap(2) system in 2019.0, Cited 23.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
Two diastereoisomers of bis(2-benzoylpyridine-O,N)dichloridonickel(II) have been isolated from the reactions of nickel(II) chloride hexahydrate and the organic ligand depending on the reaction solvent (ethanol, acetonitrile) used. DFT studies indicate that one of the isomers is more stable in both solvents, but nevertheless different diastereoisomers are crystallized from the two solvents. The two complexes represent the first pair of well characterized diastereoisomers in the coordination chemistry of 2-pyridyl ketones, providing a new example in the chemistry of octahedral MA(2)(BC) over cap (2) complexes (A = a monodentate ligand, (BC) over cap = an unsymmetrical bidentate chelate).
About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Danelli, P; Tsantis, ST; Kitos, A; Psycharis, V; Raptopoulou, CP; Tsipis, A; Perlepes, SP or concate me.. Recommanded Product: 91-02-1
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem