Kim, JH; Mertens, RT; Agarwal, A; Parkin, S; Berger, G; Awuah, SG in [Kim, Jong Hyun; Mertens, R. Tyler; Agarwal, Amal; Parkin, Sean; Awuah, Samuel G.] Univ Kentucky, Dept Chem, 505 Rose St, Lexington, KY 40506 USA; [Berger, Gilles] Univ Libre Bruxelles, Fac Pharm, Microbiol Bioorgan & Macromol Chem, Brussels, Belgium published Direct intramolecular carbon(sp(2))-nitrogen(sp(2)) reductive elimination from gold(III) in 2019.0, Cited 54.0. Formula: C12H9NO. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
The reactivity of bidentate Au-III-Cl species, [(C<^>N)AuCl2], with a bisphosphine or carbon donor ligands results in reductive elimination. Combined experimental and computational investigations lead to the first evidence of a direct intramolecular C(sp(2))-N(sp(2)) bond formation from a monomeric [(C<^>N)AuCl2] gold(iii) complex. We show that bidentate ligated Au(iii) systems bypass transmetallation to form C(sp(2))-N(sp(2)) species and NHC-Au-Cl. Mechanistic investigations of the reported transformation reveal a ligand-induced reductive elimination via a key Au-III intermediate. Kinetic studies of the reaction support a second-order rate process.
Formula: C12H9NO. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Kim, JH; Mertens, RT; Agarwal, A; Parkin, S; Berger, G; Awuah, SG or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem