Recommanded Product: 3-Pyridinecarboxaldehyde. Recently I am researching about UNACTIVATED ALKYL-HALIDES; GRIGNARD-TYPE ADDITION; C-H BONDS; CARBONYL-COMPOUNDS; ORGANIC-REACTIONS; ALPHA,BETA-UNSATURATED KETONES; QUATERNARY CENTERS; IN-SITU; ORGANOINDIUM REAGENTS; ASYMMETRIC-SYNTHESIS, Saw an article supported by the Nanjing Tech University [39837118]; Yancheng Teachers University; Nanjing Forestry University. Published in ELSEVIER SCIENCE INC in NEW YORK ,Authors: Wu, Z; Feng, XX; Wang, QD; Liu, XY; Rao, WD; Yang, JM; Shen, ZL. The CAS is 500-22-1. Through research, I have a further understanding and discovery of 3-Pyridinecarboxaldehyde
An efficient water-based bismuth-mediated addition reaction of carbonyl compound with cyclic allylic halide was developed. The reactions proceeded smoothly in aqueous DMF in the presence of ammonium iodide to afford the corresponding syn-homoallylic alcohols in moderate to good yields with excellent diastereoselectivities (>99:1 syn:anti). Reversal of product diastereoselectivity was observed when heteroaryl aldehyde possessing an adjacent chelating nitrogen atom was employed as substrate. 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
Recommanded Product: 3-Pyridinecarboxaldehyde. About 3-Pyridinecarboxaldehyde, If you have any questions, you can contact Wu, Z; Feng, XX; Wang, QD; Liu, XY; Rao, WD; Yang, JM; Shen, ZL or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem