An article Homoallylic amines as efficient chiral inducing frameworks in the conjugate addition of amides to alpha,beta-unsaturated esters. An entry to enantio-enriched diversely substituted amines WOS:000525030600018 published article about PURE LITHIUM AMIDES; TERT-BUTANESULFINYL IMINES; AZA-MICHAEL REACTION; ASYMMETRIC-SYNTHESIS; DIASTEREOSELECTIVE ADDITION; AMMONIA EQUIVALENTS; ENANTIOSELECTIVE SYNTHESIS; MEDIATED ALLYLATION; ALKALOIDS; ACCESS in [Vasse, Jean-Luc] CNRS, Inst Chim Mol Reims, UMR 7312, F-51687 Reims 2, France; Univ Reims, F-51687 Reims 2, France in 2020.0, Cited 66.0. Safety of 3-Pyridinecarboxaldehyde. The Name is 3-Pyridinecarboxaldehyde. Through research, I have a further understanding and discovery of 500-22-1
The diastereoselective conjugate addition of secondary homo-allylamines, obtained in the enantioenriched form via allylmetallation of imines, to alpha,beta-unsaturated esters is reported. This method allows access to valuable building blocks as well as heterocyclic skeletons, providing tertiary amines bearing two chains integrating a stereogenic center adjacent to the nitrogen atom.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem