SDS of cas: 91-02-1. In 2021 ORG LETT published article about ONE-STEP SYNTHESIS; FUNCTIONALIZATION; 2H-PHOSPHOLES; CHEMISTRY; AMINES in [Liu, Yanjie; Fan, Xinran; Tian, Rongqiang; Duan, Zheng] Zhengzhou Univ, Int Joint Res Lab Funct Organophosphorus Mat Hena, Green Catalysis Ctr, Int Phosphorus Lab,Coll Chem, Zhengzhou 450001, Peoples R China in 2021, Cited 52. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
We have developed an unprecedented approach for the synthesis of transient 1-phosphafulvenes through three component reactions of phospholes. The generation of 1-phosphafulvenes was demonstrated by in situ [6 + 4] cycloaddition with 2H-phospholes and [6 + 6] self-dimerization. The [6 + 4] and [6 + 6] reaction pathway could be modulated by the starting ketones and aldehydes. The construction of 1-phosphafulvenes is illustrated by a proposed mechanism combining nucleophilic addition of phospholide to the iminium or isomerized azomethine ylide and a [1,5]-shift of phosphole.
SDS of cas: 91-02-1. Welcome to talk about 91-02-1, If you have any questions, you can contact Liu, YJ; Fan, XR; Tian, RQ; Duan, Z or send Email.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem