COA of Formula: C12H9NO. Sarkar, S; Banerjee, A; Yao, W; Patterson, EV; Ngai, MY in [Ngai, Ming-Yu] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA; SUNY Stony Brook, Inst Chem Biol & Drug Discovery, Stony Brook, NY 11794 USA published Photocatalytic Radical Aroylation of Unactivated Alkenes: Pathway to beta-Functionalized 1,4-, 1,6-, and 1,7-Diketones in 2019.0, Cited 80.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
We report the development of a photocatalytic strategy for the synthesis of beta-functionalized unsymmetrical 1,4-, 1,6-, and 1,7-diketones from aroyl chlorides and unactivated alkenes at room temperature. The mild reaction conditions not only tolerate a wide range of functional groups and structural moieties, but also enable migration of a variety of distal groups including (hetero)arenes, nitrile, aldehyde, oxime derivative, and alkene. The efficiency of chirality transfer, factors that control the distal-group migration, and synthesis of carbocycles and heterocycles from the diketones are also described. Mechanistic studies suggest a reaction pathway involving a photocatalytic radical aroylation of unactivated alkenes followed by a distal-group migration, oxidation, and deprotonation to afford the desired diketones.
COA of Formula: C12H9NO. Bye, fridends, I hope you can learn more about C12H9NO, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem