An article Highly selective electrocatalytic oxidation of benzyl C-H using water as safe and sustainable oxygen source WOS:000583614600028 published article about AEROBIC OXIDATION; ANODIC-OXIDATION; ORGANIC ELECTROSYNTHESIS; N-HYDROXYPHTHALIMIDE; ELECTRON-TRANSFER; PRIMARY ALCOHOLS; REDOX CATALYSTS; P-XYLENE; EFFICIENT; HYDROCARBONS in [Sun, Yuxia; Li, Xiaoshan; Yang, Miao; Ding, Mengning] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem, Nanjing 210023, Peoples R China; [Xu, Wentao; Xie, Jin] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Jiangsu Key Lab Adv Organ Mat, Nanjing 210023, Peoples R China in 2020, Cited 78. Recommanded Product: Phenyl(pyridin-2-yl)methanone. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1
The selective oxidation of C-H bond is critical for feedstock manufacturing in chemical industry. Current strategies typically involve the use of oxygen or peroxide as the oxidation reagent under high temperature, which sets severe challenges in production sustainability and industrial safety. Herein, we demonstrate an environmental-friendly and safe electrocatalytic strategy for the selective oxidation of benzyl group to ketones at ambient conditions, while using water as the sole oxygen source. Water addition reduces the onset potential of anodic C-H oxidation, and produces 1-tetralone with satisfying conversion and excellent ketone to alcohol ratio. Layered MnO2 catalysts (with rich oxygen vacancies) further adjust the water affinity and facilitate the oxidation, leading to a significantly improved faradaic efficiency.
Recommanded Product: Phenyl(pyridin-2-yl)methanone. Welcome to talk about 91-02-1, If you have any questions, you can contact Sun, YX; Li, XS; Yang, M; Xu, WT; Xie, J; Ding, MN or send Email.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem