An article Molecular structures, spectral, electrochemical, DFT and antioxidant activities of copper(II) complexes with NNO donor Schiff base ligand WOS:000609160500005 published article about TRANSITION-METAL-COMPLEXES; X-RAY STRUCTURES; CRYSTAL-STRUCTURE; ELECTRONIC-PROPERTIES; SUPEROXIDE; BINUCLEAR; NITROGEN; MIMICS; ION; STEREOCHEMISTRY in [Singh, Yogendra Pratap; Patel, Satish Kumar] APS Univ, Dept Chem, Rewa 486003, MP, India in 2021.0, Cited 72.0. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1. Product Details of 91-02-1
The synthesis and solid state structural, spectral and electrochemical solution characterization of [Cu(L)(acpy)]ClO4 1 and [Cu(L)(NO3)]( )2 [where L = N'[(E)-phenyl(pyridin-2-yl)methylideneithiophene-2-carbohydrazide and acpy = 2,6-Diacetylpyridine] have been done by elemental analysis, UV-vis, FTIR, electrochemical techniques (CV and DPV) and electron paramagnetic resonance (epr) spectroscopy. The single crystal structures were solved by the X-ray diffraction technique. In complex 1, copper ion is in a distorted octahedral environment. The geometry of copper(II) in complex 2 is distorted square pyramidal (tau = 0.201). The mono deprotonated, HL ligand act as a tridentate to a copper(II) ion. On the basis of density functional theory (DFT) calculation, the electronic excitations involve transitions mainly from metal ligand bonding mostly the alpha-LUMO within the dominant Cu d(xy) character and to alpha-LUMO+1. Epr spectra for polycrystalline samples showed the copper(II) hyperfine features as well as half-field signal which are appropriate for Delta M-s = +/- 2 of dimers. Presence of half-field signal in 1 is due to solid-solid interaction (intra-molecular) where as in 2 the nature of interaction is intra-molecular. The antioxidant superoxide measurements show that the both complexes 1 and 2 behave as superoxide mimic in alkaline nitro blue tetrazolium chloride assay. (C) 2020 Elsevier B.V. All rights reserved.
Product Details of 91-02-1. Bye, fridends, I hope you can learn more about C12H9NO, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem