In 2022,Al-Sayed, Emir; Tanuhadi, Elias; Giester, Gerald; Rompel, Annette published an article in Acta Crystallographica, Section C: Structural Chemistry. The title of the article was 《Synthesis and characterization of the ′Japanese rice-ball′-shaped Molybdenum Blue Na4-[Mo2O2(OH)4(C6H4NO2)2]2[Mo120Ce6O366H12(OH)2(H2O)76]-200H2O》.Recommanded Product: 98-98-6 The author mentioned the following in the article:
The hybridized lanthanide-containing molybdenum blue (Ln-MB) wheel Na4[Mo2O2(OH)4(C6H4NO2)2]2[Mo120Ce6O366H12(OH)2(H2O)76]∼200H2O ({Mo2(C6H4NO2)2}2{Mo120Ce6}) was assembled in an aqueous one-pot synthesis. The Ln-MB was hybridized with 2-picolinic acid through the generation of the organometallic counter-ion [Mo2O2(OH)4(C6H4NO2)2]2+. Control experiments demonstrated that the position of the carboxylic acid group (2-position to the N atom) in the hybridization component is critical in yielding single crystals of Ln-MB. In addition to single-crystal X-ray diffraction (XRD) anal., which revealed a ′Japanese rice-ball′-shaped Ln-MB as the anion, elemental analyses, IR spectroscopy, and thermogravimetric anal. (TGA) were performed to confirm its structure and composition Bond-valence-sum calculations (BVS) revealed that ({Mo2(C6H4NO2)2}2{Mo120Ce6}) is composed of a 24-electron reduced anionic ring, which was confirmed by Vis-NIR spectroscopy. The results came from multiple reactions, including the reaction of Picolinic acid(cas: 98-98-6Recommanded Product: 98-98-6)
Picolinic acid(cas: 98-98-6) is used in the preparation of 2-Aminodihydro[1,3]thiazines as BACE 2 inhibitors and their preparation and use in the treatment of diabetes.Recommanded Product: 98-98-6