Albaneze-Walker, Jennifer; Bazaral, Charles; Leavey, Tanya; Dormer, Peter G.; Murry, Jerry A. published an article in Organic Letters. The title of the article was 《Improved Carbonylation of Heterocyclic Chlorides and Electronically Challenging Aryl Bromides》.HPLC of Formula: 116383-98-3 The author mentioned the following in the article:
Optimized conditions are described that effect the carbonylation of diverse heterocyclic chlorides to yield the desired alkyl esters. In addition, bromoanilines and bromoanisoles, which normally are poor substrates under standard carbonylation protocols, were efficiently converted to the desired products under these new conditions. The nature of the metal bidentate ligand complex was found to be critical Specifically, a correlation between ligand bite angle and catalytic efficiency is documented. In the part of experimental materials, we found many familiar compounds, such as Methyl 3-chloropicolinate(cas: 116383-98-3HPLC of Formula: 116383-98-3)
Methyl 3-chloropicolinate(cas: 116383-98-3) belongs to pyridine. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. As ligands, solvents, and catalysts they facilitate reactions; thus descriptions of these new ligands and their applications abound each year.HPLC of Formula: 116383-98-3