Chemistry is an experimental science, Name: Pyridine-2,3-dicarboxylic acid, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 89-00-9, Name is Pyridine-2,3-dicarboxylic acid, molecular formula is C7H5NO4, belongs to pyridine-derivatives compound. In a document, author is Nagaraj, K..
Microheterogeneous mediated electron transfer reaction (ETR) of surfactant cobalt(III) complexes by Fe2+ : Effect of pyridine substituent as co ligand
The outer sphere electron transfer reaction of surfactant cobalt(III) complexes, Cis[Co(en)(2)(4CNP)(C12H25NH2)](ClO4)(3) 1, Cis-[Co(trien)(4CNP)(C12H25NH2)](ClO4)(3) 2 and Cis[Co(trien)(4AMP)(C12H25NH2)](ClO4)(3) 3 (en: ethylenediamine, trien: triethylenetetramine, 4CNP: 4-cyanopyridine, 4AMP: 4-aminopyridine, C12H25NH2: dodecylamine) have been investigated by Fe2+ ion in liposome vesicles (DPPC) and ionic liquids medium at different temperatures under pseudo first order conditions using an excess of the reductant. In the presence of ionic liquid medium the second order rate constant for this electron transfer reaction was found to increase with increasing concentration of ionic liquids. Below the phase transition temperature of DPPC, the rate decreased with increasing concentration of DPPC, while above the phase transition temperature the rate increased with increasing concentration of DPPC for the same complexes has also been studied. Experimentally the reactions were found to be second order and the electron transfer postulated as outer sphere. The results have been discussed in terms of increased hydrophobic effect, self aggregation and the presence of pyridine ligand containing 4-amino and 4-cyano substituent. Crown Copyright (C) 2014 Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/).
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 89-00-9, in my other articles. Name: Pyridine-2,3-dicarboxylic acid.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem