Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Awasthi, Mahendra K., once mentioned the application of 41468-25-1, Name is (4-Formyl-5-hydroxy-6-methylpyridin-3-yl)methyl dihydrogen phosphate hydrate, molecular formula is C8H12NO7P, molecular weight is 265.1571, MDL number is MFCD00149414, category is pyridine-derivatives. Now introduce a scientific discovery about this category, Quality Control of (4-Formyl-5-hydroxy-6-methylpyridin-3-yl)methyl dihydrogen phosphate hydrate.
Low-temperature hydrogen production from methanol over a ruthenium catalyst in water
Traditionally, methanol reforming at a very high temperature (>200 degrees C) has been explored for hydrogen production. Here, we show that in situ generated ruthenium nanoparticles (ca. 1.5 nm) from an organometallic precursor promote hydrogen production from methanol in water at low temperature (90-130 degrees C), which leads to a practical and efficient approach for low-temperature hydrogen production from methanol in water. The reactivity of ruthenium nanoparticles is tuned to achieve a high rate of hydrogen gas production from methanol. Notably, the use of a pyridine-2-ol ligand significantly accelerated the hydrogen production rate by 80% to 49 mol H-2 per mol Ru per hour at 130 degrees C. Moreover, the studied ruthenium catalyst exhibits appreciably long-term stability to achieve a turnover number of 762 mol H-2 per mol Ru generating 186 L of H-2 per gram of Ru.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem