Recently I am researching about ELECTROCATALYTIC ALCOHOL OXIDATION; CATALYZED OXIDATION; HYDROCARBON OXIDATION; MOLECULAR-OXYGEN; METAL; FUNCTIONALIZATION; GREEN; CAPROLACTAMATE; CHEMISTRY; TEMPO, Saw an article supported by the Miami University; NSFNational Science Foundation (NSF) [DUE-1432466]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Marko, JA; Durgham, A; Bretz, SL; Liu, W. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. SDS of cas: 91-02-1
Oxidized products have become increasingly valuable as building blocks for a wide variety of different processes and fine chemistry, especially in the benzylic position. We report herein a sustainable protocol for this transformation through C-H functionalization and is performed using electrochemistry as the main power source and tert-butyl hydroperoxide as the radical source for the C-H abstraction. The temperature conditions reported here do not increase above 50 degrees C and use an aqueous-based medium. A broad substrate scope is explored, along with bioactive molecules, to give comparable and increased product yields when compared to prior reported literature without the use of electrochemistry.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem