Banks, Ronald Eric’s team published research in Journal of Fluorine Chemistry in 26 | CAS: 17281-59-3

Journal of Fluorine Chemistry published new progress about 17281-59-3. 17281-59-3 belongs to pyridine-derivatives, auxiliary class Pyridine,Nitrile,Salt, name is 1-(Cyanomethyl)pyridin-1-ium chloride, and the molecular formula is C7H7ClN2, Related Products of pyridine-derivatives.

Banks, Ronald Eric published the artcileFluorocarbon derivatives of nitrogen. Part 11. Synthesis of some 2-(trifluoromethyl)imidazo[1,2-a]pyridines from trifluoroacetonitrile, Related Products of pyridine-derivatives, the publication is Journal of Fluorine Chemistry (1984), 26(4), 499-506, database is CAplus.

The title compound (I; R = Me3CO2C), prepared from CF3CN and pyridinium t-butoxycarbonylmethylide, reacts smoothly with CF3CO2H to give the acid (I; R = HO2C), which was decarboxylated to I (R = H) on heating. The cyano derivative (I; R = cyano) can be obtained via treatment of CF3CN with pyridinium cyanomethylide, which is sufficiently reactive to effect nucleophilic displacement of fluorine from pentafluoropyridine under mild conditions to give II.

Journal of Fluorine Chemistry published new progress about 17281-59-3. 17281-59-3 belongs to pyridine-derivatives, auxiliary class Pyridine,Nitrile,Salt, name is 1-(Cyanomethyl)pyridin-1-ium chloride, and the molecular formula is C7H7ClN2, Related Products of pyridine-derivatives.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem