Barman, Milan K. published the artcileManganese-Catalyzed Direct Olefination of Methyl-Substituted Heteroarenes with Primary Alcohols, Formula: C11H10N4, the publication is Angewandte Chemie, International Edition (2018), 57(29), 9126-9130, database is CAplus and MEDLINE.
Herein, we present the first catalytic direct olefination of methyl-substituted heteroarenes with primary alcs. through an acceptorless dehydrogenative coupling. The reaction is catalyzed by a complex of the earth-abundant transition metal manganese that is stabilized by a bench-stable NNN pincer ligand derived from 2-hydrazinylpyridine. The reaction is environmentally benign, producing only hydrogen and water as byproducts. A large number of E-disubstituted olefins, e.g., I and II, were selectively obtained with high efficiency.
Angewandte Chemie, International Edition published new progress about 2215-33-0. 2215-33-0 belongs to pyridine-derivatives, auxiliary class Pyridine,Amine, name is 2-((2-(Pyridin-2-yl)hydrazono)methyl)pyridine, and the molecular formula is C11H10N4, Formula: C11H10N4.
Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem