7598-35-8, Name is 2-Bromopyridin-4-amine, molecular formula is C5H5BrN2, belongs to pyridine-derivatives compound, is a common compound. In a patnet, author is Sushmita, once mentioned the new application about 7598-35-8, COA of Formula: C5H5BrN2.
Triple-Bond Directed Csp(2)-N Bond Formation with N-Fluorobenzenesulfonimide as Aminating Source: One-Step Transformation of Aldehydes into Amines
A metal-free, versatile triple-bond directed approach for the decarbonylative C-H amination of ortho-alkynyl quinoline/pyridine aldehydes using N-fluorobenzenesulfonimide as nitrogen source under mild reaction conditions has been described. The designed reaction strategy was triggered by trapping of fluorine by base with subsequent attack of bis(phenylsulfonyl)-lambda(2)-azane on the carbonyl carbon of a heterocycle, which was gradually converted into the corresponding amine through a Curtius type rearrangement. This protocol provides a one-step approach for the conversion of aldehydes into amines in good yields. The synthesized amines were successfully transformed into biologically important pyrroloquinolines/pyridines.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem