Palladium complexes of sterically hindered meridonal tridentate NNN ligands was written by Broering, Martin;Kleeberg, Christian. And the article was included in Inorganica Chimica Acta in 2007.Name: 3,6-Dimethyl-2-pyridinamine This article mentions the following:
Pd(bai)(OAc) (Hbai = new 1,3-bis(arylimino)isoindoline ligands, 1,3-bis(3,6-dimethylpyridylimino)-α,α’-dimethoxyisoindoline H(3,6-MepMeOi) (5) and 1,3-bis(4-methyl-5-isopropylthiazolylimino)isoindoline H(iPrbti) (6)) were prepared from com. precursors and Pd(OAc)2 in 4 and 3 steps, resp. Pd(bai)(OAc) 7 and 8, resp., were characterized by 1H and 13C NMR spectroscopy and mass spectrometry and could be further studied by single crystal x-ray diffraction studies. The mol. structures of 7·2CHCl3 and 8 show differences in the conformational fine-tuning and unravel a higher degree of similarity with related tripyrrinates for the bti derivative 8 than for the bpi species 7. In the experiment, the researchers used many compounds, for example, 3,6-Dimethyl-2-pyridinamine (cas: 823-61-0Name: 3,6-Dimethyl-2-pyridinamine).
3,6-Dimethyl-2-pyridinamine (cas: 823-61-0) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. Several pyridine derivatives play important roles in biological systems. While its biosynthesis is not fully understood, nicotinic acid (vitamin B3) occurs in some bacteria, fungi, and mammals.Name: 3,6-Dimethyl-2-pyridinamine