Byun, Seunghwan published the artcileFluoro-imidazopyridinylidene Ruthenium Catalysts for Cross Metathesis with Ethylene, Synthetic Route of 24484-93-3, the main research area is fluoro imidazopyridinylidene ruthenium preparation catalyst alkene metathesis ethylene; crystal structure fluoro imidazopyridinylidene ruthenium preparation catalyst ethenolysis iridium; mol structure fluoro imidazopyridinylidene ruthenium preparation catalyst ethenolysis iridium; imidazopyridinylidene fluoro NHC preparation frontier MO ruthenium selenium iridium.
Ru metathesis catalysts bearing fluorinated imidazo[1,5-a]pyridin-3-ylidene carbenes (F-ImPy) were developed for ethenolysis (cross metathesis with ethylene) of Me oleate. X-ray crystal structure anal. shows Ru-F interaction, and this F substitution appears to be pivotal to have stable ImPy-Ru precatalysts. Ligand structure was varied for high catalyst activity and cross metathesis selectivity in ethenolysis reaction. F-ImPy-Ru catalysts showed high selectivity in ethenolysis of Me oleate and thermal robustness under an ethylene atm.
Organometallics published new progress about Carbene complexes, N-heterocyclic, transition metal complexes Role: CAT (Catalyst Use), PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), USES (Uses), RACT (Reactant or Reagent), PREP (Preparation). 24484-93-3 belongs to class pyridine-derivatives, name is Methyl 4-chloropicolinate, and the molecular formula is C7H6ClNO2, Synthetic Route of 24484-93-3.