Category: 104-73-4

Surface properties of the binary mixed systems of alkylpyridinium halides and sodium alkylsulfonates was written by Goralczyk, Danuta;Hac, Katarzyna;Wydro, Pawel. And the article was included in Colloids and Surfaces, A: Physicochemical and Engineering Aspects in 2003.Synthetic Route of C17H30BrN This article mentions the following:

Surface properties of the binary mixed systems of decyl- and dodecylpyridinium chloride or bromide and Na pentyl- and heptylsulfonate were studied. The surface tension of solutions of equimolar mixtures of surfactants and individual surfactants was measured, and the composition of mixed monolayers and surface interaction parameter β were calculated with the regular solution theory. Results indicate that the properties of mixed films depend on both ionic strength and the kind of added inorganic electrolyte. With the increase of inorganic electrolyte concentration, the content of more surface active ions in the adsorption films enhances and is the highest in the presence of NaI and the smallest when solutions contain NaCl. Mutual interactions in mixed adsorbed films are attractive. However, the strength of interaction weakens with the increase of ionic strength and depends on the kind of inorganic ions in the order: Cl^–>Br^–>I^–. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Synthetic Route of C17H30BrN).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Pyridine groups exist in countless molecules, and their applications include catalysis, drug design, molecular recognition, and natural product synthesis.Synthetic Route of C17H30BrN

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

A Homogeneous Mixture Composed of Vanadate, Acid, and TEMPO Functionalized Ionic Liquids for Alcohol Oxidation by H₂O₂ was written by Wang, Sa-Sa;Popovic, Zora;Wu, Hai-Hong;Liu, Ye. And the article was included in ChemCatChem in 2011.Electric Literature of C17H30BrN This article mentions the following:

Functionalized ionic liquids (ILs), such as N-(dodecyl)pyridinium vanadate (I), 1-(3-sulfopropyl)pyridinium tetrafluoroborate (II), and 2,2,6,6-tetramethyl-4-[1-oxo-3-(1-pyridinium-1-yl)propoxy]-1-piperidinyloxy tetrafluoroborate (III) were designed for a catalyst study and the synthesis of the target compounds was achieved by simple methods. A mixture of I, II and III in [Bpy]BF₄ yielded compatible IL compositions (ILCs) as a homogeneous mixture, which proved to be an efficient catalytic system for oxidation of a wide range of alcs. using H₂O₂. With the aid of II or III the catalyst could easily recovered in [Bpy]BF₄ (green chem. method) and reused for at least six runs without a loss in activity. UV/Vis spectroscopic anal. indicated that the role of 1-(3-sulfopropyl)pyridinium tetrafluoroborate was to promote the formation of the active peroxovanadium V^V species, which is responsible for substrate activation, and the role of III was to oxidize the low-valent vanadium(II-IV) species to regenerate I. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Electric Literature of C17H30BrN).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Electric Literature of C17H30BrN

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Dodecylpyridinium chloride removal by persulfate activation using UVA radiation or temperature: experimental design and kinetic modeling was written by Nunes, Roberta Frinhani;Metolina, Patricia;Teixeira, Antonio Carlos Silva Costa. And the article was included in Environmental Science and Pollution Research in 2021.Electric Literature of C17H30BrN This article mentions the following:

The degradation of dodecylpyridinium chloride (DPC) by SO₄^–· and HO· radicals, generated by UVA and thermal-activated persulfate (PS) was investigated. Temperatures of 30-50°C were used for the heat activation of PS. In the case of UVA/PS, the effects of [PS]₀ and specific photon emission rate (EP,0) were studied through a Doehlert design coupled with statistical anal. and response surface methodol. The results showed high DPC removal (99.8%) and pseudo-first-order degradation rate (k_obs = 0.0971 min^-1) for [DPC]₀ = 4.60 ± 0.11 mg L^-1, [PS]₀ = 7.75 mmol L^-1, and EP,0 = 0.437μmol photons L^-1 s^-1, with a major role of SO₄^–· radicals in comparison with HO·. The specific DPC degradation rate found under these conditions was higher than that observed for thermal activation at 50°C and [PS]₀ = 5.5 mmol L^-1 (k_obs = 0.0712 min^-1) over the same time, although complete DPC removal was also achieved in the latter. The pos. effect of EP,0 on DPC degradation by the UVA/PS process depends on PS concentrations, with kobs values increasing linearly with [PS]₀ in the range 7.75-10 mmol L^-1, whereas lower EP,0 values can be compensated by increasing [PS]₀ up to about 10 mmol L^-1, without significant scavenging. The second-order rate constants of DPC with HO· and SO₄^–·, estimated by comprehensive kinetic modeling, were 8.26 x 10⁹ and 4.44 x 10⁹ L mol^-1 s^-1, resp. Furthermore, higher [DPC]₀ would neg. affect the DPC degradation rate by the UVA/PS process, while 62% DPC removal was obtained in WWTP water, which can be considered good given the complexity of the real matrix. Finally, our results shed light on the possibility of using available UVA radiation (4.5%) in solar irradiance on the Earth’s surface, making this treatment process more sustainable and cost-effective. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Electric Literature of C17H30BrN).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. One of the examples of pyridines is the well-known alkaloid lithoprimidine, which is an A3 adenosine receptor antagonist and N,N-dimethylaminopyridine (DMAP) analog, commonly used in organic synthesis.Electric Literature of C17H30BrN

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Titrimetric determination of furosemide using aqueous-micellar solutions of surfactants was written by Kulichenko, S. A.;Fesenko, S. A.. And the article was included in Journal of Analytical Chemistry (Translation of Zhurnal Analiticheskoi Khimii) in 2002.Safety of 1-Dodecylpyridin-1-ium bromide This article mentions the following:

The solubility and acid-base properties of 4-chloro-N-(2-furylmethyl)-5-sulfamoylanthranilic acid (furosemide) were studied in aqueous-micellar solutions of surfactants of different nature. Conditions of the determination of furosemide by acid-base titration in a micellar solution of tridecylpyridinium bromide were found. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Safety of 1-Dodecylpyridin-1-ium bromide).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. The pyridine ring occurs in many important compounds, including agrochemicals, pharmaceuticals, and vitamins. Halopyridines are particularly attractive synthetic building blocks in a variety of cross-coupling methods, including the Suzuki-Miyaura cross-coupling reaction.Safety of 1-Dodecylpyridin-1-ium bromide

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

The mechanism of sonochemical degradation of a cationic surfactant in aqueous solution was written by Singla, Ritu;Grieser, Franz;Ashokkumar, Muthupandian. And the article was included in Ultrasonics Sonochemistry in 2010.Recommanded Product: 104-73-4 This article mentions the following:

The sonochem. degradation of the cationic surfactant, laurylpyridinium chloride (LPC), in water was studied at concentrations of 0.1-0.6 mM, all below its critical micelle concentration (15 mM). It has been found that the initial step in the degradation of LPC occurs primarily by a pyrolysis pathway. Chem. anal. of sonicated solutions by gas chromatog., electrospray mass spectrometry, and high performance liquid chromatog. reveals that a broad range of decomposition products, hydrocarbon gases and water-soluble species, are produced. Propionamide and acetamide were identified as two of the degradation intermediates and probably formed as the result of the opening of the pyridinium ring following OH radical addition Most of the LPC is eventually converted into carboxylic acids. The complete mineralization of these carboxylic acids by sonolysis is however a comparatively slow process due to the hydrophilic nature of these low mol. weight products. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Recommanded Product: 104-73-4).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. Pyridine is diamagnetic and has a diamagnetic susceptibility of −48.7 × 10−6 cm3·mol−1.The molecular electric dipole moment is 2.2 debyes. The standard enthalpy of formation is 100.2 kJ·mol−1 in the liquid phase and 140.4 kJ·mol−1 in the gas phase. Several pyridine derivatives play important roles in biological systems. While its biosynthesis is not fully understood, nicotinic acid (vitamin B3) occurs in some bacteria, fungi, and mammals.Recommanded Product: 104-73-4

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

How multiple noncovalent interactions regulate the aggregation behavior of amphiphilic triblock copolymer/surface-active ionic liquid mixtures was written by Luo, Haiyan;Jiang, Kun;Wang, Xiaotian;Yao, Haoyu;Liang, Xiangfeng;Li, Yingbo;Liu, Huizhou. And the article was included in Journal of Molecular Liquids in 2022.HPLC of Formula: 104-73-4 This article mentions the following:

Amphiphilic block copolymers/ionic liquids mixtures have been emerging as a new class of ‘chem. entity’ with numerous advanced applications. However, interaction mechanism governing the aggregation and the microstructure of aggregates are still far from full understanding. Herein, the role of noncovalent interactions in regulation of aggregation behaviors of mixtures of Pluronic F127 and surface-active ionic liquids, i.e. C_nmimBr, C_nPyBr and C_nMPB is investigated by DLS, cryo-TEM, NMR and mol. dynamics simulation. The interaction modes between F127 and SAILs are remarkably dependent on the concentration and cationic headgroup of SAIL. At low SAIL concentration (<CMC), mixed micelles mainly composed of F127 with some SAIL cations embedded into micelles are formed, which was primarily driven by hydrophobic interaction. However, the residence of C_nmimBr cations in micelles is quite different from that of C_nPyBr and C_nMPB cations due to its distinctive hydrogen bonding with PEO segment of F127. Upon further addition of SAILs (CSAILs > CMC), gradual disintegration of F127-rich micelles was observed due to the enhanced repulsive electrostatic force at micellar core-corona interface, accompanying with the re-formation of two types of micelles: one consisting of pure SAILs and one that SAIL micelles bound with F127 monomers via hydrogen bonding and/or hydrophobic interactions. This work provides new insight into the aggregation mechanism of these complex systems and will be helpful to rational tailoring innovative copolymers /IL-based system for specific applications. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4HPLC of Formula: 104-73-4).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. The ring atoms in the pyridine molecule are sp2-hybridized. The nitrogen is involved in the π-bonding aromatic system using its unhybridized p orbital. The lone pair is in an sp2 orbital, projecting outward from the ring in the same plane as the σ bonds. One of the examples of pyridines is the well-known alkaloid lithoprimidine, which is an A3 adenosine receptor antagonist and N,N-dimethylaminopyridine (DMAP) analog, commonly used in organic synthesis.HPLC of Formula: 104-73-4

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Adsorption of cationic and nonionic surfactants on a SiO₂ surface from aqueous solutions: 2. Adsorption of dodecylpyridinium bromide and Triton X-100 from mixed solutions was written by Kharitonova, T. V.;Ivanova, N. I.;Summ, B. D.. And the article was included in Colloid Journal in 2005.Product Details of 104-73-4 This article mentions the following:

Adsorption of cationic (dodecylpyridinium bromide) and nonionic (Triton X-100) surfactants from their mixed aqueous solutions on a SiO₂ surface at pH 3.6, 6.5, and 10 was studied by the UV spectroscopy, capillary zone electrophoresis, and wetting measurements. The adsorption of cationic and nonionic surfactants from mixed solutions is accompanied by synergistic effects manifesting themselves as an enhanced adsorption of both surfactants compared to their adsorption from individual solutions The effect of 2nd component becomes most pronounced under conditions when differences in adsorption abilities of individual surfactants are rather large (at pH 3.6 and 10). The adsorption of surfactants from mixed solutions can be controlled by the adsorption ability of components via the variations in solution pH. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Product Details of 104-73-4).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. Pyridine derivatives are also useful as small-molecule α-helix mimetics that inhibit protein-protein interactions, as well as functionally selective GABA ligands.Product Details of 104-73-4

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Synthesis, Characterization and Conductivity of Quaternary Nitrogen Surfactants Modified by the Addition of a Hydroxymethyl Substructure on the Head Group was written by Jordan, Deborah;Tan, Eng;Hegh, Dylan. And the article was included in Journal of Surfactants and Detergents in 2012.Electric Literature of C17H30BrN This article mentions the following:

Two novel series of hydroxymethyl group-appended quaternary nitrogen surfactants (QNSs) based on the aliphatic N-alkyl-trimethylammonium and aromatic N-alkylpyridinium head groups were synthesized from the appropriate nitrogen head group precursor and 1-bromoalkane. The QNSs were characterized using ¹H and ¹³C NMR and IR spectroscopy, and their purity confirmed using elemental anal. The solution behavior of the QNSs was investigated by conductivity, assessing both the aggregation concentration as well as the amount of counter-ion dissociation The results showed a general decrease in the aggregation concentration for the compounds with the hydroxymethyl addition, where the pyridinium compounds were more affected than the ammonium QNSs. In contrast, the extent of counter-ion dissociation (α) from the aggregate was slightly increased for the ammonium compounds but that of the pyridinium compounds was not generally affected by the structural modification. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Electric Literature of C17H30BrN).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. Several pyridine derivatives play important roles in biological systems. While its biosynthesis is not fully understood, nicotinic acid (vitamin B3) occurs in some bacteria, fungi, and mammals.Electric Literature of C17H30BrN

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Photo-reversibility of cinnamylidene acetic acid derived crosslinks in poly(ε-caprolactone) networks was written by Stoermann, Florian;Wischke, Christian;Lendlein, Andreas. And the article was included in MRS Online Proceedings Library in 2015.Safety of 1-Dodecylpyridin-1-ium bromide This article mentions the following:

Photoswitchable polymeric materials comprise moieties that undergo light-induced chem. reactions or conformational alteration. The reversibility of photo-responsive mol. switches has an influence on material functions observed on the macroscopic level such as reversibility of shape switching, especially with regard to the number of cycles. Cinnamylidene acetic acid (CAA) has received attention due to its reversible dimerization by [2 + 2] cycloaddition reactions. In the present study, possible side-reactions during photo-scission of the CAA dimers as netpoints in poly(ε-caprolactone) based materials were studied by fluorescence spectroscopy, HPLC and ¹H, ¹H-COSY. Liberation of fluorescent fragments, which have their origin in the various dimer structures, could only be found in small amounts, while a non-identified species seems to be generated during dimerization and photo-scission. The results furthermore suggest that CAA-based switches in PCL-networks do not provide full reversibility of netpoint formation under the examined conditions, due to non-selective side-reactions, which could lead to an attenuation of the macroscopic effect in multiple photo-cycles. In perspective, the design of CAA derivatives with enhanced photo-reversibility should be targeted. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Safety of 1-Dodecylpyridin-1-ium bromide).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. In contrast to benzene, Pyridine’s electron density is not evenly distributed over the ring, reflecting the negative inductive effect of the nitrogen atom. Pyridine derivatives are also useful as small-molecule α-helix mimetics that inhibit protein-protein interactions, as well as functionally selective GABA ligands.Safety of 1-Dodecylpyridin-1-ium bromide

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Synthesis, Characterization and Conductivity of Quaternary Nitrogen Surfactants Modified by the Addition of a Hydroxymethyl Substructure on the Head Group was written by Jordan, Deborah;Tan, Eng;Hegh, Dylan. And the article was included in Journal of Surfactants and Detergents in 2012.Electric Literature of C17H30BrN This article mentions the following:

Two novel series of hydroxymethyl group-appended quaternary nitrogen surfactants (QNSs) based on the aliphatic N-alkyl-trimethylammonium and aromatic N-alkylpyridinium head groups were synthesized from the appropriate nitrogen head group precursor and 1-bromoalkane. The QNSs were characterized using ¹H and ¹³C NMR and IR spectroscopy, and their purity confirmed using elemental anal. The solution behavior of the QNSs was investigated by conductivity, assessing both the aggregation concentration as well as the amount of counter-ion dissociation The results showed a general decrease in the aggregation concentration for the compounds with the hydroxymethyl addition, where the pyridinium compounds were more affected than the ammonium QNSs. In contrast, the extent of counter-ion dissociation (α) from the aggregate was slightly increased for the ammonium compounds but that of the pyridinium compounds was not generally affected by the structural modification. In the experiment, the researchers used many compounds, for example, 1-Dodecylpyridin-1-ium bromide (cas: 104-73-4Electric Literature of C17H30BrN).

1-Dodecylpyridin-1-ium bromide (cas: 104-73-4) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. Several pyridine derivatives play important roles in biological systems. While its biosynthesis is not fully understood, nicotinic acid (vitamin B3) occurs in some bacteria, fungi, and mammals.Electric Literature of C17H30BrN

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem