Category: 141-86-6

The author of 《Iridium Single-Atom Catalyst Performing a Quasi-homogeneous Hydrogenation Transformation of CO2 to Formate》 were Shao, Xianzhao; Yang, Xiaofeng; Xu, Jinming; Liu, Song; Miao, Shu; Liu, Xiaoyan; Su, Xiong; Duan, Hongmin; Huang, Yanqiang; Zhang, Tao. And the article was published in Chem in 2019. Application In Synthesis of 2,6-Diaminopyridine The author mentioned the following in the article:

Heterogeneous single-atom catalysts (SACs) with atomically dispersed active metal centers represent an intermediary between heterogeneous and homogeneous catalysis. In this work, a porous organic polymer with aminopyridine functionalities was designed to fabricate a stable, atomically dispersed Ir catalyst. This Ir-based SAC exhibits excellent catalytic activity during the liquid-phase hydrogenation of CO2 to formate. The associated turnover number is as high as 25,135, representing the best performance yet for a heterogeneous conversion of CO2 to formate. Spectral characterization and d. functional theory modeling demonstrate that the chem. structure of the Ir single-atom active site is analogous to that of a homogeneous mononuclear Ir pincer complex catalyst. As a result, a catalytic mechanism similar to that over a homogeneous Ir catalyst occurs during CO2 hydrogenation with this quasi-homogeneous Ir-based SAC. This work suggests a promising basis for the design of efficient SACs for the once-dominant homogeneous catalytic processes. In the experimental materials used by the author, we found 2,6-Diaminopyridine(cas: 141-86-6Application In Synthesis of 2,6-Diaminopyridine)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Application In Synthesis of 2,6-Diaminopyridine

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

In 2022,Dhiman, Nisha; Pradhan, Debabrata; Mohanty, Paritosh published an article in Fuel. The title of the article was 《Heteroatom (N and P) enriched nanoporous carbon as an efficient electrocatalyst for hydrazine oxidation reaction》.Category: pyridine-derivatives The author mentioned the following in the article:

An efficient heteroatom enriched electrocatalyst (HPHMC900) with high sp. surface area (SABET) of 1634 m2 g-1 was synthesized by calcination of heteroatom enriched inorganic-organic hybrid material (HPHM) with low SABET of 16 m2 g-1. A 100-fold increase in the SABET was observed in this heteroatom enriched carbon, which was used to investigate the catalytic activity for hydrazine oxidation reaction. The HPHMC900 showed low onset potential of 0.25 V vs R. H. E. The maximum c.d. of 96 mA cm-2 was achieved at 0.9 mV. The HPHMC900 performance was further compared with the parent material HPHM as well as other synthesized electrocatalysts, HPHMC500 and HPHMC700. These materials have shown onset potential of 0.5 V (HPHM), 0.48 V (HPHMC500) and 0.45 V (HPHMC700) vs R. H. E. Also, the performance of HPHMC900 was compared with the best performing com. 20% Pt/C electrocatalyst. The specimen has a min. Tafel slope of 14 mV dec-1 and 100% stability for 12 h without any loss of activity. The high SABET with exposed heteroatoms/active sites has contributed for the superior activity of HPHMC900 compared to other electrocatalysts investigated in this research. In the experimental materials used by the author, we found 2,6-Diaminopyridine(cas: 141-86-6Category: pyridine-derivatives)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Category: pyridine-derivatives

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

In 2022,Gui, Fukang; Jin, Qiu; Xiao, Dongdong; Xu, Xiaobin; Tan, Qinggang; Yang, Daijun; Li, Bing; Ming, Pingwen; Zhang, Cunman; Chen, Zheng; Siahrostami, Samira; Xiao, Qiangfeng published an article in Small. The title of the article was 《High-Performance Zinc-Air Batteries Based on Bifunctional Hierarchically Porous Nitrogen-Doped Carbon》.Application In Synthesis of 2,6-Diaminopyridine The author mentioned the following in the article:

Active and durable bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) on the cathode are required for high-performance rechargeable metal-air batteries. Herein, the synthesis of hierarchically porous nitrogen-doped carbon (HPNC) with bifunctional oxygen electrocatalysis for Zn-air batteries is reported. The HPNC catalyst possesses a large surface area of 1459 m2 g-1 and exhibits superior electrocatalytic activity toward ORR and OER simultaneously with a low OER/ORR overpotential of 0.62 V, taking the difference between the potential at 10 mA cm-2 for OER and half-wave potential for ORR in 0.1 M KOH. Adopting HPNC as the air cathode, primary and rechargeable Zn-air batteries are fabricated. The primary batteries demonstrate a high open-circuit potential of 1.616 V, a specific capacity of 782.7 mAh gZn-1 and a superb peak power d. of 201 mW cm-2. The rechargeable batteries can be cycled stably for over 360 cycles or 120 h at the c.d. of 5 mA cm-2. As elucidated by d. functional theory, N-doping is preferred on defective sites with pentagon configuration and on the edge in the form of pyridinic-N-type. The high content of these two motifs in HPNC leads to the superior ORR and OER activities, resp. In the experiment, the researchers used 2,6-Diaminopyridine(cas: 141-86-6Application In Synthesis of 2,6-Diaminopyridine)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Application In Synthesis of 2,6-Diaminopyridine

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

《Nitrogen-doped porous carbon nanospheres activated under low ZnCl2 aqueous system: an electrode for supercapacitor applications》 was written by Zhu, Xingxing; Huang, Xinhua; Anwer, Shoaib; Wang, Nuoya; Zhang, Lidong. Application of 141-86-6 And the article was included in Langmuir in 2020. The article conveys some information:

We reported a controlled synthesis method to obtained carbon spheres with tunable geometry under low ZnCl2 aqueous solution conditions using polytriazine as a precursor. The polytriazine precursor was polymerized by mixing/reaction of 2,6-diaminopyridine and formaldehyde in the presence of a diluted ZnCl2 aqueous system. The obtained nanospheres were then decomposed to adulterate nitrogen porous carbon nanospheres (N-PCNSs) by the decomposition and blistering process at high temperature by degrees. ZnCl2 worked as a solid-template and played the role of a stabilizing and foaming agent in the reaction. The as-prepared N-PCNSs with controllable spherical geometry, large micro-/mesoporous volume and high nitrogen content (~8.5 wt %) were employed in elec. double-layer capacitors that have a good specific capacitance (636 F/g at 1 A/g) and are long lasting. Besides, the N-PCNS delivered a high energy d. of 22.1 Wh/Kg at a power d. of 500 W/kg. In the experiment, the researchers used 2,6-Diaminopyridine(cas: 141-86-6Application of 141-86-6)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Application of 141-86-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Application In Synthesis of 2,6-DiaminopyridineIn 2020 ,《New Pyridine-Bridged Ferrocene-Rhodamine Receptor for the Multifeature Detection of Hg2+ in Water and Living Cells》 appeared in ACS Omega. The author of the article were Guo, Yu-Shuang; Zhao, Mei; Wang, Qiong; Chen, Yu-Qin; Guo, Dian-Shun. The article conveys some information:

A challenge in the design of optical and redox-active receptors is how to combine a specific recognition center with an efficient responsive system to facilely achieve multifeature detection in biol. and environmental analyses. Herein, a novel ferrocene-rhodamine receptor conjugated with a pyridine bridge was designed and synthesized. This receptor can sensitively sense Hg2+ in aqueous media via chromogenic, fluorogenic, and electrochem. multisignal outputs with a low detection limit and fast response time. Moreover, it can be qualified as a fluorescent probe for effectively monitoring Hg2+ in living cells. A plausible recognition mode was proposed and rationalized with theor. calculations In the experiment, the researchers used many compounds, for example, 2,6-Diaminopyridine(cas: 141-86-6Application In Synthesis of 2,6-Diaminopyridine)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Application In Synthesis of 2,6-Diaminopyridine

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

In 2022,Xia, Jianshe; Lee, Margaret; Santos, Peter J.; Horst, Nathan; Macfarlane, Robert J.; Guo, Hongxia; Travesset, Alex published an article in Soft Matter. The title of the article was 《Nanocomposite tectons as unifying systems for nanoparticle assembly》.Related Products of 141-86-6 The author mentioned the following in the article:

Nanocomposite tectons (NCTs) are nanocomposite building blocks consisting of nanoparticle cores functionalized with a polymer brush, where each polymer chain terminates in a supramol. recognition group capable of driving particle assembly. Like other ligand-driven nanoparticle assembly schemes (for example those using DNA-hybridization or solvent evaporation), NCTs are able to make colloidal crystal structures with precise particle organization in three dimensions. However, despite the similarity of NCT assembly to other methods of engineering ordered particle arrays, the crystallog. symmetries of assembled NCTs are significantly different. In this study, we provide a detailed characterization of the dynamics of hybridizations through universal (independent of microscopic details) parameters. We perform rigorous free energy calculations and identify the persistence length of the ligand as the critical parameter accounting for the differences in the phase diagrams of NCTs and other assembly methods driven by hydrogen bond hybridizations. We also report new experiments to provide direct verification for the predictions. We conclude by discussing the role of non-equilibrium effects and illustrating how NCTs provide a unification of the two most successful strategies for nanoparticle assembly: solvent evaporation and DNA programmable assembly. In the part of experimental materials, we found many familiar compounds, such as 2,6-Diaminopyridine(cas: 141-86-6Related Products of 141-86-6)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Related Products of 141-86-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

《Effect of Substitution at Amine Functionality of 2,6-Diaminopyridine-Coupled Rhodamine on Metal-Ion Interaction and Self-Assembly》 was written by Panja, Santanu; Mondal, Subhendu; Ghosh, Sourav; Ghosh, Utpal; Ghosh, Kumaresh. Product Details of 141-86-6 And the article was included in ACS Omega in 2020. The article conveys some information:

2,6-Diaminopyridine-coupled rhodamines I and II have been synthesized, and the effect of substitution on amine functionality toward metal-ion interactions and self-assembly is thoroughly investigated. Both the compounds effectively recognize different metal ions of biol. significance fluorimetrically and colorimetrically with a high degree of selectivity and sensitivities. While compound I is sensitive to Fe3+ ions, compound II is responsive to both Fe3+ and Al3+ ions in aqueous CH3CN (4/1, volume/volume; 10 mM tris HCl buffer, pH 6.8). The sensing mechanism involves the metal-ion chelation-induced spirolactam ring opening of the rhodamine scaffold that results in both color and fluorescence changes, while the extent of interactions with the metal ions is truly governed by the chem. structure of the compounds Both I and II are proficient in detecting Fe3+ and Al3+ ions in human lung cancer cells (A549). As new findings, unlike I, compound II formed a faint pink gel in the toluene-hexane mixture solvent (1:1, volume/volume), and the gel state of II selectively recognizes Ag+ ions by exhibiting a phase change from gel to purple soluble Exptl. findings establish the role of the formamide moiety in forming the self-assembly. In the experiment, the researchers used many compounds, for example, 2,6-Diaminopyridine(cas: 141-86-6Product Details of 141-86-6)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Product Details of 141-86-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Electric Literature of C5H7N3In 2022 ,《Ruthenium Complexes Bearing α-Diimine Ligands and Their Catalytic Applications in N-Alkylation of Amines, α-Alkylation of Ketones, and β-Alkylation of Secondary Alcohols》 was published in ACS Omega. The article was written by Gayathri, Sekar; Viswanathamurthi, Periasamy; Bertani, Roberta; Sgarbossa, Paolo. The article contains the following contents:

New Ru(II) complexes encompassing α-diimine ligands were synthesized by reacting ruthenium precursors with α-diimine hydrazones. The new ligands and Ru(II) complexes were analyzed by anal. and various spectroscopic methods. The mol. structures of L1 and complexes 1, 3, and 4 were determined by single-crystal XRD studies. The results reveal a distorted octahedral geometry around the Ru(II) ion for all complexes. Also, the new ruthenium complexes show efficient catalytic activity toward the C-N and C-C coupling reaction involving alcs. Particularly, complex 3 demonstrates effective conversion in N-alkylation of aromatic amines, α-alkylation of ketones, and β-alkylation of alcs. In the experimental materials used by the author, we found 2,6-Diaminopyridine(cas: 141-86-6Electric Literature of C5H7N3)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Electric Literature of C5H7N3

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

In 2022,Denisov, Gleb L.; Nelyubina, Yulia V. published an article in Crystals. The title of the article was 《New Co-Crystals/Salts of Gallic Acid and Substituted Pyridines: An Effect of Ortho-Substituents on the Formation of an Acid-Pyridine Heterosynthon》.Recommanded Product: 141-86-6 The author mentioned the following in the article:

Co-crystallization of gallic acid with pyridines and their polyaromatic analog, quinoline, ortho-substituted by various proton-donating groups able to form hydrogen bonds, produced the only reported co-crystal of gallic acid with an ortho-substituted pyridine, 2-hydroxypyridine, as its preferred pyridone-2 tautomer, and four new crystalline products of gallic acid. These co-crystals, or gallate salts depending on the choice of the pyridine-containing compound, as predicted by the pKa rule, were identified by X-ray diffraction to feature the popular acid-pyridine heterosynthon found in most of the two-component systems of gallic acid that lack ortho-substituents in the pyridine-containing compound This single-point heterosynthon is, however, modified by one or two proton-donating ortho-substituents, which sometimes may transform into the proton acceptors in an adopted tautomer or zwitterion, to produce its two- or other multi-point variants, including a very rare four-point heterosynthon. The hydrogen bonds they form with the gallic acid species in the appropriate co-crystals/salts strongly favors the formation of the acid-pyridine heterosynthon over the acid-acid homosynthon. In the competitive conditions of multi-component systems, such a modification might be used to reduce supramol.-synthon-based polymorphism to produce new pharmaceuticals and other crystalline materials with designed properties. In the experimental materials used by the author, we found 2,6-Diaminopyridine(cas: 141-86-6Recommanded Product: 141-86-6)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Recommanded Product: 141-86-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

《Efficient synthesis of highly dispersed ultrafine Pd nanoparticles on a porous organic polymer for hydrogenation of CO2 to formate》 was published in RSC Advances in 2020. These research results belong to Shao, Xianzhao; Miao, Xinyi; Yu, Xiaohu; Wang, Wei; Ji, Xiaohui. Electric Literature of C5H7N3 The article mentions the following:

Precise design of catalytic supports is an encouraging technique for simultaneously improving the activity and stability of the catalyst. However, development of efficient heterogeneous catalysts for transforming CO2 into formic acid (FA) is still a big challenge. Herein, we report that Pd nanoparticles (NPs) based on a porous organic polymeric support containing amide and pyridine functional groups (AP-POP) can be an efficient catalyst for selective hydrogenation of CO2 to form formate with high efficiency even under mild reaction conditions (6.0 MPa, 80°C). Electron d. of the active Pd species modulated via the interaction between pyridine nitrogen and Pd play important roles in dramatic enhancement of catalytic activity and was indicated by XPS along with CO chemisorption. This work provides an interesting and effective strategy for precise support design to improve the catalytic performance of nanoparticles. The results came from multiple reactions, including the reaction of 2,6-Diaminopyridine(cas: 141-86-6Electric Literature of C5H7N3)

2,6-Diaminopyridine(cas: 141-86-6) belongs to pyridine. Pyridine and its simple derivatives are stable and relatively unreactive liquids, with strong penetrating odours that are unpleasant.Electric Literature of C5H7N3

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem