Category: 47369-00-6

Higashi, Tomohiro published the artcileTwo Sharp Phase Change Processes of Diphenyl Viologen at a Au(111) Electrode Surface: Non-Faradaic Transition with Interplay of Ionic Adsorption of Chloride and Bromide and Faradaic One, Synthetic Route of 47369-00-6, the publication is Journal of Physical Chemistry C (2015), 119(3), 1320-1329, database is CAplus.

Two phase change processes of di-Ph viologen (dPhV) on a Au(111) electrode in KCl and KBr aqueous solutions were described using the results of voltammetric, electroreflectance (ER), and electrochem. scanning tunneling microscopic (EC-STM) measurements. Both processes exhibited sharp spikelike voltammetric responses. In KCl solution, the phase change at 0.30 V vs. Ag/AgCl/saturated KCl is a nonfaradaic order-disorder phase transition, from an ordered adlayer of dPhV dication (dPhV²⁺) with coadsorbed Cl^– at more pos. potentials than 0.30 V to a gas-like phase at less pos. potentials. The faradaic reaction at -0.09 V is the transition from the gaslike phase to a condensed monolayer of dPhV^â€?. The EC-STM images of the condensed monolayer showed stripe patterns of rows of π-π stacked dPhV^â€?. Almost the same set of two processes was observed in KBr solution but not in KF solution In KF solution, although two voltammetric responses were observed, the peaks were small and broad, indicative of sluggish adsorption state changes of individual dPhV cations. Taken together, specific adsorption of coexistent anions is of critical importance for the occurrence of the sharp nonfaradaic phase transition.

Journal of Physical Chemistry C published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, Synthetic Route of 47369-00-6.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Imai, Yoshitane published the artcileCharge-transfer host system composed of 9,10-bis(3,5-dihydroxyphenyl)anthracene and methylviologen, Product Details of C22H18Cl2N2, the publication is Tetrahedron (2009), 65(18), 3740-3744, database is CAplus.

By using 9,10-bis(3,5-dihydroxyphenyl)anthracene as an electron donor and 1,1′-dimethyl-4,4′-bipyridinium dichloride as an electron acceptor, a spontaneously resolved charge-transfer (CT) complex is formed. This CT complex can include n-alkyl alc. mols. as guests, and the DRS of this CT complex change with the type of component guest mols.

Tetrahedron published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, Product Details of C22H18Cl2N2.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Imai, Yoshitane published the artcileFormation of chiral charge-transfer complex with axially chiral 1,1′-bi-2-naphthol and viologen derivatives, Computed Properties of 47369-00-6, the publication is Tetrahedron Letters (2006), 47(21), 3603-3606, database is CAplus.

By using three types of viologen derivatives, we synthesized chiral charge-transfer (CT) complexes with an axially chiral 1,1′-bi-2-naphthol mol. and successfully controlled the crystal structure and inclusion ability of the third component by changing the viologens.

Tetrahedron Letters published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, Computed Properties of 47369-00-6.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Katagiri, Takayuki published the artcileVisible light-induced reduction properties of diphenylviologen with water-soluble porphyrin, Related Products of pyridine-derivatives, the publication is Journal of Photochemistry and Photobiology, A: Chemistry (2018), 368-373, database is CAplus.

Mol. conversion reaction system containing a dye and a biocatalyst catalyzing a reaction of a carbon-carbon bond formation from CO₂ as a feedstock were constructed. For example, NADP-malic enzyme (ME, EC1.1.1.40) catalyzes the reaction of introducing CO₂ as a carboxy group to pyruvate (C3 compound) to form malate (C4 compound) via oxaloacetate in the presence of natural co-enzyme NADPH. In a recent study, visible light-induced oxaloacetate production from pyruvate and CO₂ with the system consisting an electron donor, a photosensitizer, diphenylviologen (PV²⁺) derivative as an electron mediator and ME was reported. However, the visible light-induced reduction properties of PV²⁺ with water-soluble Zn porphyrin have not been clarified. In this study, chem. and photo-redox properties of PV²⁺ were studied. In addition, to produce malate, CO₂ saturated reaction solution containing triethanolamine, tetraphenylporphine tetrasulfonate (H₂TPPS), pyruvate, PV²⁺ and ME in the presence of Mg²⁺, co-factor for ME was irradiated with visible-light, the oxaloacetate and malate were produced.

Journal of Photochemistry and Photobiology, A: Chemistry published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, Related Products of pyridine-derivatives.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Wu, Guanglu published the artcileQuantitative Supramolecular Heterodimerization for Efficient Energy Transfer, Name: 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, the publication is Angewandte Chemie, International Edition (2020), 59(37), 15963-15967, database is CAplus and MEDLINE.

The challenge of quant. forming self-assembled heterodimers without other equilibrium byproducts is overcome through self-sorting favored by the introduction of designed shape-complementary moieties. Such a supramol. strategy based on cucurbit[8]uril-directed dimerization is further applied to generate hetero-chromophore dimers quant., leading to efficient energy transfer (>85%) upon photoexcitation.

Angewandte Chemie, International Edition published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C9H22OSi, Name: 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Tsuruta, Keisuke published the artcileElectrochemical Condensation of Methylviologen on Specifically-adsorbed Anion Layers, Product Details of C22H18Cl2N2, the publication is Electroanalysis (2019), 31(6), 1150-1154, database is CAplus.

The adsorption of methylviologen dications (MV²⁺) on single-crystalline Au electrodes in both H₂SO₄ and HClO₄ was examined MV²⁺ strongly interacted with sulfate and bisulfate anions adsorbed on the Au(111) electrode surface in 0.05 M H₂SO₄ under a controlled potential of 1.25 V vs. the reversible hydrogen electrode (RHE). A characteristic non-Faradaic current was observed at 1.10 V vs. RHE. When adsorption of MV²⁺ was carried out in 0.1 M HClO₄, the electrochem. response of MV²⁺ was less than that obtained in H₂SO₄. The results show that the formation of a highly ordered sulfate/bisulfate adlayer plays an important role in the formation of condensed MV²⁺ layers. Examination of polycrystalline Au and Au(100) electrodes revealed a poor electrochem. response due to the surface roughness of the Au substrate, but the electrochem. detection was applicable to polycrystalline Au electrodes. A systematic investigation of the structural dependency of viologen derivatives showed that mol. size is important for electrostatic interactions with a highly ordered sulfate/bisulfate adlayer. The findings of the present study demonstrate successful detection of MV²⁺ at a concentration of â‰? pM with a non-Faradaic current.

Electroanalysis published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C6H9BN2O2, Product Details of C22H18Cl2N2.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Mochida, Tomoyuki published the artcileAssembled structures and magnetic properties of viologen-[M(mnt)₂] charge-transfer salts (mnt = maleonitriledithiolate; M = Cu, Ni, Pt), HPLC of Formula: 47369-00-6, the publication is Inorganica Chimica Acta (2012), 111-116, database is CAplus.

Ion-pair compounds of phenyl-substituted viologen dications with [M(mnt)₂] dianions (mnt = maleonitriledithiolate) were prepared and characterized. (Benzyl viologen)[M(mnt)₂] (M = Cu (1), Ni (2), Pt (3)) and (Ph viologen)[Cu(mnt)₂] (4) exhibited mixed-stack crystal structures, whereas (dinitrophenyl viologen)[Cu(mnt)₂] (5) exhibited no π-π interactions. Magnetic susceptibility measurements revealed that 1 exhibits a ferromagnetic exchange interaction (Weiss constant θ = +0.9 K), possibly mediated by the diamagnetic cation. Antiferromagnetic interactions were observed for 4 (θ = -2.0 K) and 5 (θ = -2.9 K), whereas 2 and 3 were diamagnetic. Absorption bands assignable to charge transfer were observed in the mixed-stack salts in the visible to near-IR region.

Inorganica Chimica Acta published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, HPLC of Formula: 47369-00-6.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Weitz, Ernst published the artcileFree ammonium radicals. VI. Radicals and meriquinonoid compounds. I. The dipyridinium subhalides, Application In Synthesis of 47369-00-6, the publication is Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen (1926), 432-45, database is CAplus.

cf. C. A. 18, 2168. It was suggested in the earlier paper that the deeply colored compounds assumed by other investigators to be dimeric quinhydrones (I) consisting of 1 mol. dipyridinium dihalide + 1 mol. dihydrodipyridyl (II) are in reality monomol. mono- or subhalides (III) of the dipyridinium radical (IV), a valence-tautomeric form of II. Mol. weight determinations of dibenzylpyridinium subchloride (V) in boiling MeOH gave mean values corresponding to 0.5 that calculated for III, indicating that the V in solution is almost completely ionized into IV and Cl^–; these determinations have been repeated in a perfected apparatus, in which the mol. weight of N,N’-diphenyldipyridinium subchloride (VI) has also been determined; the new determinations fully confirm the older observations. The higher result for V obtained by Emmert, Jungek and Häffner (C. A. 19, 518), from which they conclude that it is a I and ionizes into 3 parts (complex cation and 2 Cl ions) are explained by the fact that they used more concentrated solutions To establish that in their own solutions there is only electrolytic dissociation and not “quinhydrone decomposition,” W. and F. determined whether Beer’s law held for their solutions of V, using a specially constructed apparatus which made it possible to exclude every trace of atm. O; no lightening in the color could be detected either on dilution or heating. The IV are assumed to be univalent radicals in which the “odd” electron oscillates about the 2 central γ-C atoms. The anion in “bridged” union with the 2 halves of the IV need not be taken into account in these considerations; (see structure) it may be fixed at any point of the mol. or crystal lattice, the necessary oscillation in the affinity distribution being taken care of by the “odd” electron. This conception of a vibrating electron, which differs from older oscillation theories, especially that of Baeyer, in that it is only electrons and not atoms which are assumed to vibrate, can be applied to many other so-called intramol. quinhydrones, i. e. to large classes of dyes like those of the Ph₃CH series. A N,N’-dibenzyl-γ,γ’-dipyridinium “two-thirds”-iodide, C₂₄H₂₂N₂I₂.2C₂₄H₂₂N₂ (VII), was occasionally obtained instead of the normal III on treating the radical with the diiodide, but the formation of this and similar polymol. compounds is not at all contrary to the monomol. formulation of the III, for both the dipyridinium salts (with their coordinately unsaturated N atoms) and the radicals have enough unsaturated positions at which addition of other mols. can take place. The b. p. apparatus was so constructed that the determinations could be made in an atm. (not in a current) of CO₂ exactly under atm. pressure. Using 0.93 as the b. p. constant of the MeOH, the mol. weight of Bz₂ was found in this apparatus to be 192-226 (mean of 11 determinations, 210; calculated, 210); of PhNHAc, 139-44 (mean of 6 determinations, 142; calculated 135); of V in N/17.1-N/47.0 solution, 172-220 (mean of 18 determinations, 197); in N/11.5-N/15.3 solution, 203-229 (mean of 4 determinations, 215; calculated for III/2, 187); of VI in N/21.3-N/22.9 solution, 172-6 (mean of 3 determinations, 174; calculated for III/2, 173). On the other hand, dibenzyldipyridinium dichloride gave mol. weights of 253, 243 and 238 for V 31.3, 15.6 and 41.7, resp. (calculated for C₂₄H₂₂N₂Cl₂/2, 204). That the III represent an entirely independent stage of oxidation is further confirmed by the fact that they dissolve without decomposition in AcOH (at room temperature) while the corresponding free radicals dissolve only with decomposition VI, prepared like the subiodide, forms steel-blue crystals with violet tinge and metallic luster. VII forms a dark violet, indistinctly crystalline mass.

Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C6H8N2, Application In Synthesis of 47369-00-6.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Evans, Jeffrey C. published the artcileAn electron spin resonance, ENDOR, and TRIPLE resonance study of methyl-substituted N,N’-diphenyl-4,4′-bipyridylium dichloride radical cations, COA of Formula: C22H18Cl2N2, the publication is Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) (1985), 315-18, database is CAplus.

The ESR and ENDOR spectra of the radical cations of the bipyridylium dichlorides I (R = H, Me, R¹ = R² = R³ = H; R = R² = R³ = H, R¹ = Me; R = R¹ = R³ = H, R² = Me; R = R² = R³ = Me, R¹ = H) (II–VI, resp.) in MeOH were studied over a range of temperatures Values for the hyperfine coupling constants at -40° are given. The radical cation concentrations of II–V decreased with decreasing temperature, this change being reversible, whereas that of VI did not. The reversible change with temperature is explained in terms of a monomer-dimer equilibrium, and the absence of such an equilibrium for VI is due to lack of planarity of the mol., because of steric hindrance between the Me groups and the pyridyl ortho protons. The thermodn. constants ΔG°, ΔH°, and ΔS°, obtained for the dimerization equilibrium, are reported.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, COA of Formula: C22H18Cl2N2.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem

Geraskina, Margarita R. published the artcileThe Viologen Cation Radical Pimer: A Case of Dispersion-Driven Bonding, SDS of cas: 47369-00-6, the publication is Angewandte Chemie, International Edition (2017), 56(32), 9435-9439, database is CAplus and MEDLINE.

The π bonds between organic radicals have generated excitement as an orthogonal interaction for designing self-assembling architectures in water. A systematic investigation of the effect of the viologen cation radical structure on the strength and nature of the pimer bond is provided. A striking and unexpected feature of this π bond is that the bond strength is unchanged by substitution with electron-donating groups or withdrawing groups or with increased conjugation. Furthermore, the interaction is undiminished by sterically bulky N-alkyl groups. Theor. modeling indicates that strong dispersion forces dominate the interaction between the radicals, rationalizing the insensitivity of the bonding interaction to substituents: the stacking of polarizable π radicals leads to attractive dispersion forces in excess of typical dispersion interactions of small mols. and helps overcome the Coulombic repulsion of bringing two cationic species into contact.

Angewandte Chemie, International Edition published new progress about 47369-00-6. 47369-00-6 belongs to pyridine-derivatives, auxiliary class Pyridine,Salt,Benzene,Organic ligands for MOF materials,Nitrogen containing MOF ligands,Nitrogen containing MOF ligands, name is 1,1′-Diphenyl-[4,4′-bipyridine]-1,1′-diium chloride, and the molecular formula is C22H18Cl2N2, SDS of cas: 47369-00-6.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem