Category: 65350-59-6

Investigation of the solute-solute and solute-solvent interactions in ternary {saccharide + ionic liquid + water} systems was written by Zafarani-Moattar, Mohammed Taghi;Shekaari, Hemayat;Mazaher Haji Agha, Elnaz. And the article was included in Journal of Molecular Liquids in 2018.Recommanded Product: 1-Butyl-4-methylpyridin-1-ium bromide This article mentions the following:

The aim of this work is to investigate the salt effect resulted by addition of ionic liquids to aqueous saccharide solutions To achieve this goal, systematic studies have been made on ternary {saccharide + ionic liquid + water} system using the available vapor-liquid equilibrium (VLE) data published recently. Vapor pressure depression, osmotic and activity coefficient data for the ionic liquids and saccharides in the binary solutions are used to investigate ionic liquid-water and saccharide-water interactions. For ternary solutions, the calculated activity coefficient of saccharides in presence of ionic liquids, transfer Gibbs energies, pair and triplet interaction parameters and salting constants are used to investigate saccharide-ionic liquid interactions.. The aforementioned properties were also calculated for these new systems. In this article, the effect of stereochem. of sugar, cation (imidazolium or pyridinium), chain length and anion of ionic liquids on vapor-liquid equilibrium behavior of these ternary systems and saccharide-ionic liquid interactions have been discussed. Generally, we found that there is a relationship between soluting-in or soluting-out behavior of ionic liquids and their hydration so that soluting-in effect is observed in ionic liquids with longer chain length and with anions having smaller values of osmotic coefficient From the VLE results we conclude that soluting-out effect of ionic liquids also depends on the hydration of saccharides and is observed in saccharides with high tendency to interact with water. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6Recommanded Product: 1-Butyl-4-methylpyridin-1-ium bromide).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridine has a conjugated system of six π electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. Many analogues of pyridine are known where N is replaced by other heteroatoms . Substitution of one C–H in pyridine with a second N gives rise to the diazine heterocycles (C4H4N2), with the names pyridazine, pyrimidine, and pyrazine.Recommanded Product: 1-Butyl-4-methylpyridin-1-ium bromide

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Measurement and correlation on solubility of acetaminophen in aqueous solutions of 1-octyl-3-methyl imidazolium bromide, 1-butyl-4-methyl pyridinium bromide and 1-octyl-4-methyl pyridinium bromide was written by Mehrdad, Abbas;Taeb, Sara;Ehsani-Tabar, Sahar;Hossein Miri, Amir. And the article was included in Journal of Chemical Thermodynamics in 2020.Electric Literature of C10H16BrN This article mentions the following:

Aqueous solubility of acetaminophen in the presence of 1-octyl-3-Me imidazolium bromide, 1-butyl-4-Me pyridinium bromide and 1-octyl-4-Me pyridinium bromide ionic liquid, as co-solvent was investigated at different temperatures and mass fraction of ionic liquid The obtained results reveal that the solubility of acetaminophen was increased by increasing temperature and concentration of ionic liquid Solubility of ACP was significantly increased when mass fraction of 1-octyl-3-Me imidazolium bromide and 1-octyl-4-Me pyridinium bromide reaches to more than 0.05. The possible reasons behind enhanced solubility of ACP in aqueous solution of ionic liquid are hydrophobic interaction and the formed micelles by cations of ionic liquid Thermodn. functions of dissolution were calculated by Van’t Hoff equation. The exptl. solubility of acetaminophen was correlated with the modified Wilson and the electrolyte-NRTL models as activity coefficient model. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6Electric Literature of C10H16BrN).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. One of the examples of pyridines is the well-known alkaloid lithoprimidine, which is an A3 adenosine receptor antagonist and N,N-dimethylaminopyridine (DMAP) analog, commonly used in organic synthesis.Electric Literature of C10H16BrN

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Pillar[5]arene-Containing Metallacycles and Host-Guest Interaction Caused Aggregation-Induced Emission Enhancement Platforms was written by Tuo, Wei;Sun, Yan;Lu, Shuai;Li, Xiaopeng;Sun, Yao;Stang, Peter J.. And the article was included in Journal of the American Chemical Society in 2020.Related Products of 65350-59-6 This article mentions the following:

Coordination-driven Pt metallacycles have shown potential in controllable modular self-assembly, which has made a vital contribution to biomedicine, catalysis, and multiresponsive materials. Herein, pillar[5]arene units were integrated into one skeleton through coordination-driven self-assembly, resulting in the formation of a hexagonal Pt(II) metallacycle decorated with six pillar[5]arenes. The host-guest interactions of the as-prepared metallacycle (pillar[5]arenes as hosts) and 1-butyl-4-[4-(diphenylamino)styryl]pyridinium (guest) were investigated. The metallacycle was found to facilitate the coaggregation between the guests and pillar[5]arenes through a synergistic effect, thus engendering a sharp increase in fluorescence intensity. The resultant aggregate was investigated by DLS and TEM. Our studies imply that the pillar[5]arene-containing metallacycle can serve as a potential platform for realizing emission enhancement effects. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6Related Products of 65350-59-6).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridine’s the lone pair does not contribute to the aromatic system but importantly influences the chemical properties of pyridine, as it easily supports bond formation via an electrophilic attack. One of the examples of pyridines is the well-known alkaloid lithoprimidine, which is an A3 adenosine receptor antagonist and N,N-dimethylaminopyridine (DMAP) analog, commonly used in organic synthesis.Related Products of 65350-59-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors was written by Wragg, David S.;Fullerton, Grace M.;Byrne, Peter J.;Slawin, Alexandra M. Z.;Warren, John E.;Teat, Simon J.;Morris, Russell E.. And the article was included in Dalton Transactions in 2011.Product Details of 65350-59-6 This article mentions the following:

The authors have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relation between this and sodalite, which can be synthesized in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6Product Details of 65350-59-6).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Product Details of 65350-59-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Insight into the mechanism of oxidative kinetic resolution of racemic secondary alcohols by using manganese(III)(salen) complexes as catalysts was written by Li, Zhen;Tang, Zhong H.;Hu, Xiao X.;Xia, Chun G.. And the article was included in Chemistry – A European Journal in 2005.HPLC of Formula: 65350-59-6 This article mentions the following:

The oxidative kinetic resolution of various racemic secondary alcs. with PhI(OAc)₂ catalyzed by chiral [Mn^III(salen)] complexes in the presence of KBr was studied in a water/organic solvent mixture The dramatic, synergetic effect of additives, organic solvent, and the substituents of chiral salen ligands on the enantioselectivities of the reactions is reported. Results from UV/Vis spectroscopy and ESI-MS studies provide evidence that these reactions are induced by the formation of a high-valent manganese intermediate. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6HPLC of Formula: 65350-59-6).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. HPLC of Formula: 65350-59-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Insight into the mechanism of oxidative kinetic resolution of racemic secondary alcohols by using manganese(III)(salen) complexes as catalysts was written by Li, Zhen;Tang, Zhong H.;Hu, Xiao X.;Xia, Chun G.. And the article was included in Chemistry – A European Journal in 2005.HPLC of Formula: 65350-59-6 This article mentions the following:

The oxidative kinetic resolution of various racemic secondary alcs. with PhI(OAc)₂ catalyzed by chiral [Mn^III(salen)] complexes in the presence of KBr was studied in a water/organic solvent mixture The dramatic, synergetic effect of additives, organic solvent, and the substituents of chiral salen ligands on the enantioselectivities of the reactions is reported. Results from UV/Vis spectroscopy and ESI-MS studies provide evidence that these reactions are induced by the formation of a high-valent manganese intermediate. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6HPLC of Formula: 65350-59-6).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. HPLC of Formula: 65350-59-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem

Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors was written by Wragg, David S.;Fullerton, Grace M.;Byrne, Peter J.;Slawin, Alexandra M. Z.;Warren, John E.;Teat, Simon J.;Morris, Russell E.. And the article was included in Dalton Transactions in 2011.Product Details of 65350-59-6 This article mentions the following:

The authors have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relation between this and sodalite, which can be synthesized in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented. In the experiment, the researchers used many compounds, for example, 1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6Product Details of 65350-59-6).

1-Butyl-4-methylpyridin-1-ium bromide (cas: 65350-59-6) belongs to pyridine derivatives. Pyridines are an important class of heterocycles and occur in polysubstituted forms in many naturally occurring biologically active compounds, drug molecules and chiral ligands. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Product Details of 65350-59-6

Referemce:
Pyridine – Wikipedia,
Pyridine | C5H5N – PubChem