Chaplin, Adrian B.’s team published research in Organometallics in 30 | CAS: 338800-13-8

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C23H43NP2, Application In Synthesis of 338800-13-8.

Chaplin, Adrian B. published the artcile[Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound, Application In Synthesis of 338800-13-8, the publication is Organometallics (2011), 30(16), 4466-4469, database is CAplus.

An expedient new route to the cationic [(PNPtBu)Rh(L)]+ metal fragments (PNPtBu = κ3-NC5H3-2,6-(CH2P tBu2)2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H2)][BArF4]. [(PNPR)Rh(PCy3)][BArF4] (R = Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C23H43NP2, Application In Synthesis of 338800-13-8.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem