An article High-Pressure-Mediated Thiourea-Organocatalyzed Asymmetric Michael Addition to (Hetero)aromatic Nitroolefins: Prediction of Reaction Parameters by PCP-SAFT Modelling WOS:000544057700023 published article about ION-EXCHANGE-RESIN; ACETIC-ACID; CATALYZED ESTERIFICATION; LACTIC-ACID; CHEMICAL-EQUILIBRIUM; COSOLVENT INFLUENCE; REACTION-KINETICS; SOLVENTS; NITROMETHANE; REDUCTION in [Weinbender, Thomas; Reiser, Oliver] Univ Regensburg, Inst Organ Chem, Univ Str 31, D-93053 Regensburg, Germany; [Knierbein, Michael; Bittorf, Lukas; Held, Christoph; Sadowski, Gabriele] TU Dortmund Univ, Lab Thermodynam, Emil Figge Str 70, D-44227 Dortmund, Germany; [Siewert, Riko; Verevkin, Sergey P.] Univ Rostock, Dept Phys Chem, Dr Lorenz Weg 1, D-18059 Rostock, Germany in 2020.0, Cited 74.0. The Name is 3-Pyridinecarboxaldehyde. Through research, I have a further understanding and discovery of 500-22-1. Recommanded Product: 3-Pyridinecarboxaldehyde
Thiourea-organocatalyzed Michael additions of diethyl malonate to various heteroaromatic nitroolefins (13 examples) have been studied under high-pressure (up to 800 MPa) and ambient pressure conditions. High pressure was conducive to enhanced product yields by a factor of 2-12 at a given reaction time, high reaction rates (reaction times were decreased from 72-24 h down to 4-24 h) and high enantioselectivity. Elucidating the effects of solvents for maximizing reaction rates and yields has been carried out using the Perturbed-Chain Polar Statistical Associating Fluid Theory (PCP-SAFT), allowing for the first time a prediction of the kinetic profiles under high-hydrostatic-pressure conditions.
About 3-Pyridinecarboxaldehyde, If you have any questions, you can contact Weinbender, T; Knierbein, M; Bittorf, L; Held, C; Siewert, R; Verevkin, SP; Sadowski, G; Reiser, O or concate me.. Recommanded Product: 3-Pyridinecarboxaldehyde
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem