Das, Prasenjit’s team published research in ACS Catalysis in 6 | CAS: 89076-64-2

ACS Catalysis published new progress about 89076-64-2. 89076-64-2 belongs to pyridine-derivatives, auxiliary class Pyridine,Nitro Compound,Benzene, name is 5-Nitro-2-phenylpyridine, and the molecular formula is C11H8N2O2, COA of Formula: C11H8N2O2.

Das, Prasenjit published the artcileAerobic Direct C(sp2)-H Hydroxylation of 2-Arylpyridines by Palladium Catalysis Induced with Aldehyde Auto-Oxidation, COA of Formula: C11H8N2O2, the publication is ACS Catalysis (2016), 6(9), 6050-6054, database is CAplus.

Herein we present a Pd-catalyzed direct C-H hydroxylation of 2-arylpyridines using mol. oxygen (O2) as the sole oxidant. The key aspects of the method include: (a) the activation of mol. oxygen with a nontoxic and inexpensive aldehyde; (b) an efficient association of the in situ-generated acyl peroxo radical with palladium catalysis; and (c) convenient operating conditions. On the basis of the results obtained in a series of control experiments, a PdII/PdIV catalytic cycle is implicated for the transformations. Furthermore, the method offers an easy access to a broad range of substituted 2-(pyridin-2-yl)phenols in good isolated yields.

ACS Catalysis published new progress about 89076-64-2. 89076-64-2 belongs to pyridine-derivatives, auxiliary class Pyridine,Nitro Compound,Benzene, name is 5-Nitro-2-phenylpyridine, and the molecular formula is C11H8N2O2, COA of Formula: C11H8N2O2.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem