In 2022,Das, Sanjit; Nugegoda, Dinesh; Yao, Wenzhi; Qu, Fengrui; Figgins, Matthew T.; Lamb, Robert W.; Webster, Charles Edwin; Delcamp, Jared H.; Papish, Elizabeth T. published an article in European Journal of Inorganic Chemistry. The title of the article was 《Sensitized and Self-Sensitized Photocatalytic Carbon Dioxide Reduction Under Visible Light with Ruthenium Catalysts Shows Enhancements with More Conjugated Pincer Ligands》.Application In Synthesis of 4,4′-Dimethyl-2,2′-bipyridine The author mentioned the following in the article:
A new method to synthesize complexes of the type [(CNC)RuII(NN)L]n+ has been introduced, where CNC is a tridentate pincer composed of two (benz)imidazole derived NHC rings and a pyridyl ring, NN is a bidentate aromatic diimine ligand, L=bromide or acetonitrile, and n=1 or 2. Following this new method a series of six new complexes has been synthesized and characterized by spectroscopic, analytic, crystallog., and computational methods. Their electrochem. properties have been studied via cyclic voltammetry under both N2 and CO2 atmospheres. Photocatalytic reduction of CO2 to CO was performed using these complexes both in the presence (sensitized) and absence (self-sensitized) of an external photosensitizer. This study evaluates the effect of different CNC, NN, and L ligands in sensitized and self-sensitized photocatalysis. Catalysts bearing the benzimidazole derived CNC pincer show much better activity for both sensitized and self-sensitized photocatalysis as compared to catalysts bearing the imidazole derived CNC pincer. Furthermore, self-sensitized photocatalysis requires a diimine ligand for CO2 reduction with catalyst 2ACN being the most active catalyst in this series with TON=85 and TOF=22 h-1 with an electron donating 4,4′-dimethyl-2,2′-bipyridyl (dmb) ligand and a benzimidazole derived CNC pincer. In addition to this study using 4,4′-Dimethyl-2,2′-bipyridine, there are many other studies that have used 4,4′-Dimethyl-2,2′-bipyridine(cas: 1134-35-6Application In Synthesis of 4,4′-Dimethyl-2,2′-bipyridine) was used in this study.
4,4′-Dimethyl-2,2′-bipyridine(cas: 1134-35-6) is used as a chemical Intermediate. It can be used for the determination of ferrous and cyanide compounds.Application In Synthesis of 4,4′-Dimethyl-2,2′-bipyridine Furthermore, 4,4′-Dimethyl-2,2′-bipyridine is used in the synthesis of a series of o-phenanthroline-substituted ruthenium(II) complexes.