Cyclometallated compounds. XIII. Cyclopalladation of 2-phenoxypyridine and structurally-related compounds was written by de Geest, Duncan J.;O’Keefe, Brendan J.;Steel, Peter J.. And the article was included in Journal of Organometallic Chemistry in 1999.Name: 2-Phenoxypyridine This article mentions the following:
2-Phenoxypyridine and 2-phenylsulfanylpyridine are cyclopalladated readily by Pd acetate to give six-membered metallocycles. Extension to the three isomeric bis(2-pyridyloxy)benzenes leads to doubly-cyclopalladated compounds In contrast, 3,6-diphenoxypyridazine and 4,6-diphenoxypyrimidine only undergo monopalladation, while their S analogs are resistant to cyclopalladation. All cyclometalated compounds are converted to their acetylacetonate derivatives and the x-ray crystal structure of one of these is described. In the experiment, the researchers used many compounds, for example, 2-Phenoxypyridine (cas: 4783-68-0Name: 2-Phenoxypyridine).
2-Phenoxypyridine (cas: 4783-68-0) belongs to pyridine derivatives. The ring atoms in the pyridine molecule are sp2-hybridized. The nitrogen is involved in the 锜?bonding aromatic system using its unhybridized p orbital. The lone pair is in an sp2 orbital, projecting outward from the ring in the same plane as the 锜?bonds. Pyridine, its benzo and pyridine-based compounds play diverse roles in organic chemistry. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Name: 2-Phenoxypyridine