De Vos, Arthur; Lejaeghere, Kurt; Muniz Miranda, Francesco; Stevens, Christian V.; Van Der Voort, Pascal; Van Speybroeck, Veronique published the artcile< Electronic properties of heterogenized Ru(II) polypyridyl photoredox complexes on covalent triazine frameworks>, Reference of 366-18-7, the main research area is electronic property heterogenized ruthenium polypyridyl photoredox complex covalent triazine.
Ru(II) polypyridyl complexes have been successful for a wide range of photoredox applications thanks to their efficient light-induced metal-to-ligand charge transfer. Using the computational framework of d.-functional theory, we report how these complexes can be anchored onto covalent triazine frameworks while maintaining their favorable electronic properties. We moreover show that variation of the nitrogen content of the framework linkers or complex ligands endows the heterogenized catalyst with a unique versatility, spanning a wide range of absorption characteristics and redox potentials. By judiciously choosing the catalyst building blocks, it is even possible to selectively guide the charge transfer toward either the scaffold or the accessible pore sites. Rational design of sustainable and efficient photocatalysts thus comes within reach.
Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about Coordination compounds Role: CAT (Catalyst Use), SPN (Synthetic Preparation), TEM (Technical or Engineered Material Use), USES (Uses), PREP (Preparation). 366-18-7 belongs to class pyridine-derivatives, and the molecular formula is C10H8N2, Reference of 366-18-7.