Patel, AK; Jadeja, RN; Roy, H; Patel, RN; Patel, SK; Butcher, RJ; Cortijo, M; Herrero, S in [Patel, A. K.; Jadeja, R. N.] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Chem, Vadodara 390002, India; [Roy, H.] Maharaja Sayajirao Univ Baroda, Fac Sci, Dept Zool, Vadodara 390002, India; [Patel, R. N.; Patel, S. K.] APS Univ, Dept Chem, Rewa 486003, MP, India; [Butcher, R. J.] Howard Univ, Dept Inorgan & Struct Chem, Washington, DC 20059 USA; [Cortijo, M.; Herrero, S.] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Inorgan, Madrid 28040, Spain published Copper(II) hydrazone complexes with different nuclearities and geometries: Synthesis, structural characterization, antioxidant SOD activity and antiproliferative properties in 2020.0, Cited 107.0. Name: Phenyl(pyridin-2-yl)methanone. The Name is Phenyl(pyridin-2-yl)methanone. Through research, I have a further understanding and discovery of 91-02-1.
New copper(II) hydrazone complexes with (Z)-2-(phenyl(2-(pyridin-2-yl)hydrazono)methyl)pyridine (L) were synthesized and characterized using various physicochemical methods. The geometries of the complexes can be classified as mononuclear and binuclear. The complex 1, [Cu(L)(Cl)(2)], is mononuclear whereas the solid-state structure of complex 2 contain a mixture of co-crystals of the mono- and binuclear complexes 2a, [Cu(L)(H2O)(SO4)], and 2b, [Cu-2(L)(2)(mu-SO4)(2)]. The unit cell of 2 contains two units of the mononuclear complex 2a and one units of the binuclear complex 2b. The copper atoms contained in all the mono- and binuclear complexes are in a distorted square pyramidal geometry. The present study indicates that complexes having different nuclearities and geometries can be achieved by changing the synthetic conditions and methods. Variable temperature magnetic susceptibility measurements of the complexes have shown the presence of weak anti-ferromagnetic interactions. These interactions are mediated by intermolecular hydrogen bonding in 1 and through a symmetric sulfate bridge in 2. The EPR spectra in the polycrystalline state for 1 and 2 exhibited a broad signal at similar to 2.149 due to spin-spin interactions between two copper(II) ions. The cyclic voltammograms of complexes 1 and 2 in DMSO gave two irreversible redox waves. Density functional theory (DFT) calculations were evaluated in the study, involving the molecular specification with the use of B3LYP/LANL2DZ formalism for the copper atoms and B3LYP/6-31G for the remaining atoms. Both complexes catalyzed the dismutation of superoxide (O-2(center dot-)). Furthermore, the copper complexes and the ligand were tested to explore their anticancer properties. Promising cytotoxicity of the synthesized compounds was observed against the selected cancerous cell lines of neuroblastoma, lung carcinoma, hepatocellular carcinoma and breast cancer. (C) 2020 Elsevier Ltd. All rights reserved.
Name: Phenyl(pyridin-2-yl)methanone. About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Patel, AK; Jadeja, RN; Roy, H; Patel, RN; Patel, SK; Butcher, RJ; Cortijo, M; Herrero, S or concate me.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem