Recently I am researching about INDUCED EMISSION; FLUORESCENCE; COMPLEXES; REDUCTION; LIGANDS; ANALOGS, Saw an article supported by the Natural Sciences and Engineering Research Council (NSERC) of CanadaNatural Sciences and Engineering Research Council of Canada (NSERC) [DG RGPIN-2015-04814, RGPIN-2015-04298, RGPIN-2018-04240]; Ontario Ministry of Research and Innovation (ERA)Ministry of Research and Innovation, Ontario [ER-14-10-147]; Canadian Foundation for Innovation (JELF) [33977]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Cappello, D; Therien, DAB; Staroverov, VN; Lagugne-Labarthet, F; Gilroy, JB. The CAS is 91-02-1. Through research, I have a further understanding and discovery of Phenyl(pyridin-2-yl)methanone. Application In Synthesis of Phenyl(pyridin-2-yl)methanone
We develop the chemistry of boron difluoride hydrazone dyes (BODIHYs) bearing two aryl substituents and explore their properties. The low-energy absorption bands (lambda(max)=427-464 nm) of these dyes depend on the nature of the N-aryl groups appended to the BODIHY framework. Electron-donating and extended pi-conjugated groups cause a redshift, whereas electron-withdrawing groups result in a blueshift. The title compounds were weakly photoluminescent in solution and strongly photoluminescent as thin films (lambda(PL)=525-578 nm) with quantum yields of up to 18 % and lifetimes of 1.1-1.7 ns, consistent with the dominant radiative decay through fluorescence. Addition of water to THF solutions of the BODIHYs studied causes molecular aggregation which restricts intramolecular motion and thereby enhances photoluminescence. The observed photoluminescence of BODIHY thin films is likely facilitated by a similar molecular packing effect. Finally, cyclic voltammetry studies confirmed that BODIHY derivatives bearing para-substituted N-aryl groups could be reversibly oxidized (E-ox1=0.62-1.02 V vs. Fc/Fc(+)) to their radical cation forms. Chemical oxidation studies confirmed that para-substituents at the N-aryl groups are required to circumvent radical decomposition pathways. Our findings provide new opportunities and guiding principles for the design of sought-after multifunctional boron difluoride complexes that are photoluminescent in the solid state.
About Phenyl(pyridin-2-yl)methanone, If you have any questions, you can contact Cappello, D; Therien, DAB; Staroverov, VN; Lagugne-Labarthet, F; Gilroy, JB or concate me.. Application In Synthesis of Phenyl(pyridin-2-yl)methanone
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem