Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 13161-30-3, Name is 2-Pyridinol-1-oxide, molecular formula is C5H5NO2, belongs to pyridine-derivatives compound, is a common compound. In a patnet, author is Agnarelli, Laura, once mentioned the new application about 13161-30-3, Computed Properties of C5H5NO2.
Facile nucleophilic substitution of coordinated acetonitrile in trans-[PtCl4(NCMe)(PPh3)]
( )Despite the generally accepted inertness of platinum(IV) complexes towards nucleophilic substitution, the title compound promptly reacts with nucleophiles L (L = pyridine, quinoline, isoquinoline, benzothiazole, o-, m-, ptoluidine) affording the corresponding acetonitrile substitution products. To follow the reaction spectroscopically, a series of platinum(IV) standards were prepared by bridge splitting of trans-[Pt(mu-Cl)Cl(PPh3)](2), followed by oxidation by PhICl2. All the new platinum(II) and platinum(IV) complexes were fully characterized, and, in some cases, the structure was studied by single crystal X-ray diffraction. Even when protic o-, m- and p-toluidines were used, chemoselectivity towards substitution was observed, with addition products formed in less than 10% extent.
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Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem