Fernandez-Salas, Jose A.; Manzini, Simone; Piola, Lorenzo; Slawin, Alexandra M. Z.; Nolan, Steven P. published an article in 2014, the title of the article was Ruthenium catalysed C-H bond borylation.Synthetic Route of 1349171-28-3 And the article contains the following content:
An easily prepared series of phenylindenyldihydridosilyl ruthenium complexes (2a-2d) was obtained by reaction of tertiary silanes with the com.-available [RuCl(3-phenylindenyl)(PPh3)2] (1). The [RuH2(3-phenylindenyl)(SiEt3)] (2a) complex was shown to be highly efficient (1.5 mol%) in the ortho-selective borylation of pyridyl substrates, with yields of up to 90%. A novel ruthenium(IV)-catalyzed C-H activation borylation/functionalization reaction using a remarkably low catalyst loadings is described. The experimental process involved the reaction of 2-(2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)pyridine(cas: 1349171-28-3).Synthetic Route of 1349171-28-3
The Article related to phenylindenyldihydridosilyl ruthenium complex preparation catalyst borylation, Organometallic and Organometalloidal Compounds: Group Viii – Co, Ni, Ru, Rh, Pd, Os, Ir, Pt and other aspects.Synthetic Route of 1349171-28-3