Reference of 175358-01-7, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 175358-01-7, Name is 3-Amino-6-chloropicolinamide, SMILES is O=C(N)C1=NC(Cl)=CC=C1N, belongs to pyridine-derivatives compound. In a article, author is Vaddypally, Shivaiah, introduce new discover of the category.
Transition-metal-mediated reduction and reversible double-cyclization of cyanuric triazide to an asymmetric bitetrazolate involving cleavage of the six-membered aromatic ring
Cyanuric triazide reacts with several transition metal precursors, extruding one equivalent of N-2 and reducing the putative diazidotriazeneylnitrene species by two electrons, which rearranges to N-(1 ‘ H-[1,5 ‘-bitetrazol]-5-yl)methanediiminate (biTzI(2-)) dianionic ligand, which ligates the metal and dimerizes, and is isolated from pyridine as [M(biTzI)](2)Py-6 (M = Mn, Fe, Zn, Cu, Ni). Reagent scope, product analysis, and quantum chemical calculations were combined to elucidate the mechanism of formation as a two-electron reduction preceding ligand rearrangement.
Reference of 175358-01-7, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 175358-01-7.
Reference:
Pyridine – Wikipedia,
,Pyridine | C5H5N – PubChem