Gibson, Dorothy H.’s team published research in Organometallics in 23 | CAS: 338800-13-8

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C23H43NP2, Related Products of pyridine-derivatives.

Gibson, Dorothy H. published the artcileSynthesis and Characterization of Ruthenium(II) Hydrido and Hydroxo Complexes Bearing the 2,6-Bis(di-tert-butylphosphinomethyl)pyridine Ligand, Related Products of pyridine-derivatives, the publication is Organometallics (2004), 23(10), 2510-2513, database is CAplus.

The reaction of [Ru(CO)2Cl2]n with 2,6-bis(di-tert-butylphosphinomethyl)pyridine (PNP) and then anion exchange yields [Ru(PNP)(CO)2Cl]PF6 (1). Reaction of 1 with AgBF4, in acetone, followed by MeCN and then anion exchange gave [Ru(PNP)(CO)2(MeCN)](PF6)2 (2); reaction of 2 with H2O gave [Ru(PNP)(CO)2OH]PF6 (3), whereas reaction of 2 with aqueous KOH led to [Ru(PNP)(CO)(MeCN)H]PF6 (4). Complexes 3 and 4 were characterized by x-ray crystal structure anal.

Organometallics published new progress about 338800-13-8. 338800-13-8 belongs to pyridine-derivatives, auxiliary class Bis-phosphine Ligands, name is 2,6-Bis((di-tert-butylphosphino)methyl)pyridine, and the molecular formula is C23H43NP2, Related Products of pyridine-derivatives.

Referemce:
https://en.wikipedia.org/wiki/Pyridine,
Pyridine | C5H5N – PubChem