《Metal-Free Direct Nucleophilic Perfluoroalkylthiolation with Perfluoroalkanesulfenamides》 was written by Glenadel, Quentin; Bordy, Mathieu; Alazet, Sebastien; Tlili, Anis; Billard, Thierry. Recommanded Product: 31106-82-8This research focused ontrifluoromethylthiol preparation; perfluoroalkanesulfenamide halide perfluoroalkylthiolation. The article conveys some information:
A practical method to generate RFS- (R = CF3, CF2CF3, CF2CF2CF3) anions in situ from shelf-stable reagents, which were initially designed for electrophilic reactions has been reported. With an “”iodide activation”” step, these in situ released anions can directly participate in metal-free nucleophilic substitution reactions with the loss of various leaving groups. This method is compatible with various functional groups and provides good yields. With this strategy, the first direct nucleophilic perfluoroalkylthiolation reactions have been described. In the experimental materials used by the author, we found 2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8Recommanded Product: 31106-82-8)
2-(Bromomethyl)pyridine hydrobromide(cas: 31106-82-8) belongs to pyridine. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Additionally, pyridine-based natural products continue to be discovered and studied for their properties and to understand their biosynthesis.Recommanded Product: 31106-82-8