Gong, Zhiming; Wang, Ru; Jiang, Yue; Kong, Xiangyu; Lin, Yue; Xu, Zhengjie; Zhou, Guofu; Liu, Jun-Ming; Kempa, Krzysztof; Gao, Jinwei published an article in 2021. The article was titled 《Novel D-A-D type small-molecular hole transport materials for stable inverted perovskite solar cells》, and you may find the article in Organic Electronics.HPLC of Formula: 624-28-2 The information in the text is summarized as follows:
Hole transport materials (HTMs), as a critical role in the hole extraction and transportation processes, highly influence the efficiency and stability of perovskite solar cells (PSCs). Despite that several efficient dopant-free HTMs have been reported, there is still no clear structure-property relationship that could give instructions for the rational mol. design of efficient HTMs. Thus, in this work, a series of donor-acceptor-donor (D-A-D) type carbazole-based small mols., TM-1 to TM-4, have been carefully designed and synthesized. By varing the electron acceptor unit from benzene to pyridine, pyrazine and diazine, their packing structure in single crystals, optical and electronic properties have shown a great difference. While as dopant-free HTM in p-i-n type PSCs, TM-2 improved the device photovoltaic performance with a power conversion efficiency from 15.02% (based on PEDOT:PSS) to 16.13%. Moreover, the unencapsulated device based on TM-2 retains about 80% of its initial efficiency after 500 h storage in ambient environment, showing the superior stability.2,5-Dibromopyridine(cas: 624-28-2HPLC of Formula: 624-28-2) was used in this study.
2,5-Dibromopyridine(cas: 624-28-2) belongs to pyridine. Pyridines form stable salts with strong acids. Pyridine itself is often used to neutralize acid formed in a reaction and as a basic solvent. HPLC of Formula: 624-28-2