Kinetics of methyl chloroformate ethanolysis in presence of pyridine 1-oxides was written by Grabarnik, M. S.;Chimishkyan, A. L.;Orlov, S. I.;Burmistrov, S. Yu.. And the article was included in Organic Reactivity (Tartu) in 1990.Recommanded Product: 3718-65-8 This article mentions the following:
A kinetic study of ClCO2Me ethanolysis in the presence of pyridine 1-oxides was interpreted in terms of general base and nucleophilic catalysis. The effect of substituents in the pyridine ring was described by a Yukawa-Tsuno equation. In the experiment, the researchers used many compounds, for example, 3,5-Dimethylpyridine 1-oxide (cas: 3718-65-8Recommanded Product: 3718-65-8).
3,5-Dimethylpyridine 1-oxide (cas: 3718-65-8) belongs to pyridine derivatives. The ring atoms in the pyridine molecule are sp2-hybridized. The nitrogen is involved in the 锜?bonding aromatic system using its unhybridized p orbital. The lone pair is in an sp2 orbital, projecting outward from the ring in the same plane as the 锜?bonds. Pyridine derivatives are also useful as small-molecule 浼?helix mimetics that inhibit protein-protein interactions, as well as functionally selective GABA ligands.Recommanded Product: 3718-65-8